Basic Chemistry

Matter and Energy

      Matter occupies space and has mass

states:

      Energy

does not occupy space or have mass
has capacity to do work

potential energy:  stored energy

kinetic energy:  energy that is doing work

forms:

mechanical

chemical

electrical

      Composition of matter

elements:  different types of matter

atom:  smallest unit of an element

      atomic number:  protons per atom

      mass number:  protons + neutrons

isotopes:  atoms of an element with different numbers of neutrons

      radioisotopes are unstable isotopes

      on decay they release either particles or energy or both

atomic weight:  not the same as atomic mass

      Molecule:  two or more atoms held together by a chemical bond

compounds

mixtures

      solutions

      molarity

      Chemical bonds

electrons

ionic bonds

      anions

      cations

covalent bonds

      polar molecules

      nonpolar molecules

hydrogen bonds

      Chemical reactions

occur when atoms combine with or separate from other atoms

involve making or breaking bonds between atoms

types of reactions

      chemical equations

      synthesis:  two molecules combine to form a larger molecule

      decomposition:  a large molecule is broken down into smaller molecules

      exchange:  combination of synthesis & decomposition

      oxidation-reduction (redox) reactions

            electron donor is oxidized

            electron acceptor is reduced

reversibility of reactions

Biochemistry

inorganic compounds

      water

            high heat capacity

            high heat of vaporization

            polarity

      ionic compounds

            dissociation:  ionic compounds separate when placed in water

            ions:  atoms or molecules with electrical charges

            salt:  anion + cation (other than H+)

            electrolytes:  conduct electrical current through solutions

                        acids:  ionic compounds that release H+ (protons)

                        bases:  ionic compounds that pick up H+ (protons)

                        pH measures relative concentration of H+ in solutions

                        pH = -log10[H+]

                        pH scale:  0, 7, 14

            buffer

organic molecules:  based on rings or chains of carbon

                                           carbon is electroneutral

      carbohydrates (sugars and starches)

            monosaccharides

                                        glucose, fructose, galactose

            disaccharides

                                                       sucrose

            polysaccharides

                                                starch, glycogen

      lipids

            neutral fats/triglycerides

                                         oils (unsaturated) vs. fats

            phospholipids

            steroids

                        cholesterol, estrogen, testosterone

            eicosanoids

                        prostaglandins

      proteins

            amino acids

                              tyrosine, tryptophan, serine, leucine, &c

            peptides/polypeptides/proteins

                                 myosin, trypsin, adrenocorticotropin

            fibrous vs. globular proteins

                        collagen, hemoglobin

            enzymes

                        formation of enzyme-substrate complex

                        reduction of activation energy by internal rearrangements

                        release of products

                        cofactors

      nucleic acids

            building blocks:  nucleotides

                   adenine, thymine (DNA), uracil (RNA),guanine, cytosine

            DNA:  deoxyribose + nucleotide = nucleoside

            RNA:  ribose

      ATP:  adenosine triphosphate

            ~-bond:  adenine-ribose-PO4~PO3~PO3

            phosphorylation-dephosphorylation



Links