| Konstantin Tsiolkovsky |
|---|
| Welcome to lifeform.org and lifeform.net, home of the Tsiolkovsky Group, |
| a space for Individuals dedicated to the realization of Hydrogen and Oxygen |
| powered, single stage to orbit, manned Space Colonization and development. |
Save the Earth - Develop Space
| History of Rocket Science | |||
|---|---|---|---|
| Konstantin Tsiolkovsky | Russia | 1903 | Original Space Flight Concepts |
| Robert Goddard | America | 1917 | Initial Theory and Experiments |
| Hermann Oberth | Germany | 1923 | Initial Theory |
| Werner von Braun | Germany | 1939 | First Operational Rocket/V2 |
| America | 1961 | F1/J2/Saturn/Apollo Program | |
| Sergey Korolyov | Russia | 1957 | R-7/Vostok/Soyuz |
| Krafft Ehricke | America | 1961 | RL-10/Centaur Upper Stage |
| Paul Castenholz | America | 1971 | SSME/Space Shuttle Main Engine |
| Present Rocket Science Assets - 2005 | |||
|---|---|---|---|
| Space Shuttle Main Engine | SSME | 1981 | 350+ SSME Flights |
| Space Transportation System | STS | 1981 | Space Shuttle Infrastructure |
| International Space Station/Soyuz | ISS | 2001 | Operational and Functional |
| Boeing Delta IV Medium Upper Stage Rocketdyne RS-68 Pratt & Whitney RL-10B-2 | 2001 | Hydrogen Powered Two Stage to Orbit Launch Vehicle | |
| Future Rocket Science Goals - 2010 |
|---|
| Human rate the Boeing Delta IV medium rocket. Build two human rated launch pads at SLC-37A/B. |
| Convert Space Shuttle VAB and launch pad for single space shuttle main engines in a straight stack. |
| Demonstrate the first single stage to orbit flight using single space shuttle main engines - SSTO. |
| Demonstrate the first fully reusable launch vehicle using single space shuttle main engines - RLV. |
| Demonstrate full flow staged combustion engine - integrated powerhead demonstrator program - IPD. |
| Hydrogen/Oxygen Engine Comparison | |||
|---|---|---|---|
| Cryogenic Engine | SSME (109%) | RS-68 | ET (Ideal) |
| Launcher Usage | Space Shuttle | Delta IV | SSTO/RLV |
| Engine Weight | 7,480 lbs. | 14,560 lbs. | 7,500 lbs. |
| Sea Level Thrust | 418,660 lbf. | 650,000 lbf. | 650,000 lbf. |
| Vacuum Thrust | 512,950 lbf. | 745,000 lbf. | 750,000 lbf. |
| Chamber Pressure | 3,008 psia. | 1,410 psia. | 3,000 psia. |
| Specific Impulse - Isp | 452 seconds | 410 seconds | 450 seconds |
| Nozzle Area Ratio | 69 : 1 | 25.1 : 1 | 70 : 1 |
| Thrust to Weight Ratio | 68.6 : 1 | 51 : 1 | 100 : 1 |
Instant Human - Just Add Coffee
Save the Earth - Develop Space
| n | H | 2e | Compounds | p | 2h | H | He | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| He | Li | Be | Molecules | B | C | N | O | F | Ne | |||||||||
| Ne | Na | Mg | Solutions | Al | Si | P | S | Cl | Ar | |||||||||
| Ar | K | Ca | Sc | Ti | V | Cr | Mn | Fe | Co | Ni | Cu | Zn | Ga | Ge | As | Se | Br | Kr |
| Kr | Rb | Sr | Y | Zr | Nb | Mo | Tc | Ru | Rh | Pd | Ag | Cd | In | Sn | Sb | Te | I | Xe |
| Xe | Cs | Ba | La | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg | Tl | Pb | Bi | |||
| Ce | Pr | Nd | Pm | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu |
|---|
| a' | a | b' | b | c | d' | d | e' | e | f | g' | g |
|---|
Radio Waves - Microwaves - Infrared - Optical - Ultraviolet - X-Rays - Gamma Rays
| Hydrogen |
| Phonons | Photons |
| Heat | Light | Energy |
| Proton | Neutron | Electron |
| Water | Oxygen | Hydrogen | Water |
| Elements | Molecules | Compounds | Solutions |
| Inert Gases | Helium | Neon | Argon | Krypton | Xenon |
| Organics | Hydrogen | Carbon | Oxygen | Nitrogen | Phosphorus |
| Alkali Metals | Lithium | Sodium | Potassium | Rubidium | Cesium |
| Alkaline Earth Metals | Beryllium | Magnesium | Calcium | Strontium | Barium |
| Rare Earth Metals | Scandium | Yttrium | Lanthanum | Cerium | Lanthanides |
| Transition Metals | Titanium | Vanadium | Chromium | Manganese | Refractories |
| Industrial Metals | Iron | Cobalt | Nickel | Copper | Zinc |
| Technical Metals | Aluminum | Gallium | Indium | Tin | Lead |
| Noble Metals | Nickel | Palladium | Platinum | Silver | Gold |
| Heavy Metals | Cadmium | Mercury | Thallium | Lead | Bismuth |
| Refractories | Zirconium | Niobium | Molybdenum | Ruthenium | Rhodium |
| Hafnium | Tantalum | Tungsten | Rhenium | Osmium | Iridium |
| Lanthanides | Lanthanum | Cerium | Praseodymium | Neodymium |
| Samarium | Europium | Gadolinium | Terbium | Dysprosium |
| Holmium | Erbium | Thulium | Ytterbium | Lutetium |
| Group III Elements | Boron | Aluminum | Gallium | Indium | Thallium |
| Group IV Elements | Carbon | Silicon | Germanium | Tin | Lead |
| Group V Elements | Nitrogen | Phosphorus | Arsenic | Antimony | Bismuth |
| Semiconductors | Silicon | Germanium | Arsenic | Boron | Phosphorus |
| Chalcogenides | Oxygen | Sulfur | Selenium | Tellurium | Electron |
| Halide Salts | Hydrogen | Fluorine | Chlorine | Bromine | Iodine |
| Organics | Hydrogen | Carbon | Nitrogen | Oxygen | Phosphorus |
| Inert Gases | Helium | Neon | Argon | Krypton | Xenon |
| Hydrides | ||
|---|---|---|
| Water - H2O | Ammonia - NH3 | Methane - CH4 |
| Molecular Gases | |||
|---|---|---|---|
| Hydrogen - H2 | Oxygen - O2 | Nitrogen - N2 | Argon - Arn |
| Oxides | ||
|---|---|---|
| Carbonate - CO3 | Silicate - SiO2 | Borate - BO3 |
| Carbon Dioxide - CO2 | Silicon Dioxide - SiO2 | Boric Acid - H3BO3 |
| Calcium Nitrate - Ca(NO3)2. 4(H2O) | Magnesium Sulfate - MgSO4. 7(H2O) |
| Potassium Hydroxide - KOH |
| Bismuth (I) Iodide - BiI |
Table 5. The computed Spectroscopic properties of BiI (the excitation energy, Te, the equilibrium bond length, re, and the vibrational frequency, we) together with corresponding experimental data.
| State | Te (cm-1) | re (Å) | we (cm-1) | |||
|---|---|---|---|---|---|---|
| Calc. | Exp. | Calc. | Exp. | Calc. | Exp. | |
| C13S-0+ | 0 | 0 | 2.886 | 2.805 | 156 | 164 |
| C23S-1 | 5096 | 6182 | 2.878 | - | 152 | 169 |
| a1D2 | 12336 | - | 2.861 | - | 155 | - |
| B0+ (III) | 24148 | 23389 | 2.898 | - | 170 | 198 |
| 0+ (IV) | 25691 | - | 3.095 | - | 217 | - |
Scientific and Technical Acronyms, Symbols and Abbreviations
A Mental Note : These tables are not yet Unicoded. In order to properly view these tables, you must have your Symbol Fonts enabled. Thus this page is best viewed in Firefox 2.0.0.20, whereas in Firefox 3.0+ the symbol fonts are completely borked.
| Character Map - Times New Roman | |||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| # | 32 | 33 | 34 | 35 | 36 | 37 | 38 | 39 | 40 | 41 | 42 | 43 | 44 | 45 | 46 | 47 | 48 | 49 | 50 | 51 | 52 | 53 | 54 | 55 | 56 | 57 | 58 | 59 | 60 | 61 | 62 | 63 | # |
| 32 | ! | " | # | $ | % | & | ' | ( | ) | * | + | , | - | . | / | 0 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | : | ; | < | = | > | ? | 63 | |
| 64 | @ | A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | [ | \ | ] | ^ | _ | 95 |
| 96 | ` | a | b | c | d | e | f | g | h | i | j | k | l | m | n | o | p | q | r | s | t | u | v | w | x | y | z | { | | | } | ~ | | 127 |
| 128 | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | 160 | |
| 160 | | ¡ | ¢ | £ | ¤ | ¥ | ¦ | § | ¨ | © | ª | « | ¬ | | ® | ¯ | ° | ± | ² | ³ | ´ | µ | ¶ | · | ¸ | ¹ | º | » | ¼ | ½ | ¾ | ¿ | 191 |
| 192 | À | Á | Â | Ã | Ä | Å | Æ | Ç | È | É | Ê | Ë | Ì | Í | Î | Ï | Ð | Ñ | Ò | Ó | Ô | Õ | Ö | × | Ø | Ù | Ú | Û | Ü | Ý | Þ | ß | 223 |
| 224 | à | á | â | ã | ä | å | æ | ç | è | é | ê | ë | ì | í | î | ï | ð | ñ | ò | ó | ô | õ | ö | ÷ | ø | ù | ú | û | ü | ý | þ | ÿ | 255 |
| # | 224 | 225 | 226 | 227 | 228 | 229 | 230 | 231 | 232 | 233 | 234 | 235 | 236 | 237 | 238 | 239 | 240 | 241 | 242 | 243 | 244 | 245 | 246 | 247 | 248 | 249 | 250 | 251 | 252 | 253 | 254 | 255 | # |
| Character Map - Symbol | |||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| # | 32 | 33 | 34 | 35 | 36 | 37 | 38 | 39 | 40 | 41 | 42 | 43 | 44 | 45 | 46 | 47 | 48 | 49 | 50 | 51 | 52 | 53 | 54 | 55 | 56 | 57 | 58 | 59 | 60 | 61 | 62 | 63 | # |
| 32 | ! | " | # | $ | % | & | ' | ( | ) | * | + | , | - | . | / | 0 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | : | ; | < | = | > | ? | 63 | |
| 64 | @ | A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | [ | \ | ] | ^ | _ | 95 |
| 96 | ` | a | b | c | d | e | f | g | h | i | j | k | l | m | n | o | p | q | r | s | t | u | v | w | x | y | z | { | | | } | ~ | | 127 |
| 128 | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | 160 |
| 160 | | ¡ | ¢ | £ | ¤ | ¥ | ¦ | § | ¨ | © | ª | « | ¬ | | ® | ¯ | ° | ± | ² | ³ | ´ | µ | ¶ | · | ¸ | ¹ | º | » | ¼ | ½ | ¾ | ¿ | 191 |
| 192 | À | Á | Â | Ã | Ä | Å | Æ | Ç | È | É | Ê | Ë | Ì | Í | Î | Ï | Ð | Ñ | Ò | Ó | Ô | Õ | Ö | × | Ø | Ù | Ú | Û | Ü | Ý | Þ | ß | 223 |
| 224 | à | á | â | ã | ä | å | æ | ç | è | é | ê | ë | ì | í | î | ï | | ñ | ò | ó | ô | õ | ö | ÷ | ø | ù | ú | û | ü | ý | þ | | 255 |
| # | 224 | 225 | 226 | 227 | 228 | 229 | 230 | 231 | 232 | 233 | 234 | 235 | 236 | 237 | 238 | 239 | 240 | 241 | 242 | 243 | 244 | 245 | 246 | 247 | 248 | 249 | 250 | 251 | 252 | 253 | 254 | 255 | # |
| Greek Alphabet | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Greek | Symbol | Letter | Greek | Symbol | Letter | ||||
| Alpha | A | a | A | a | Nu | N | n | N | n |
| Beta | B | b | B | b | Xi | X | x | X | x |
| Gamma | G | g | G | g | Omicron | O | o | O | o |
| Delta | D | d | D | d | Pi | P | p | P | p |
| Epsilon | E | e | E | e | Rho | R | r | R | r |
| Zeta | Z | z | Z | z | Sigma | S | s | S | s |
| Eta | H | h | H | h | Tau | T | t | T | t |
| Theta | Q | q | Q | q | Upsilon | U | u | U | u |
| Iota | I | i | I | i | Phi | F | f | F | f |
| Kappa | K | k | K | k | Chi | C | c | C | c |
| Lambda | L | l | L | l | Psi | Y | y | Y | y |
| Mu | M | m | M | m | Omega | W | w | W | w |
| Metric Prefixes | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Prefix | Symbol | ´ | Value | Prefix | Symbol | ´ | Value | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| - | - | 100 | one | - | - | 100 | one | deka | da | 101 | ten | deci | d | 10-1 | tenth | hecto | h | 102 | hundred | centi | c | 10-2 | hundredth | kilo | k | 103 | thousand | milli | m | 10-3 | thousandth | mega | M | 106 | million | micro | m | 10-6 | millionth | giga | G | 109 | billion | nano | n | 10-9 | billionth | tera | T | 1012 | trillion | pico | p | 10-12 | trillionth | peta | P | 1015 | quadrillion | femto | f | 10-15 | quadrillionth | exa | E | 1018 | zillion | atto | a | 10-18 | zillionth | zetta | Z | 1021 | bizillion | zepto | z | 10-21 | bizillionth | yotta | Y | 1024 | godzillion | yocto | y | 10-24 | godzillionth | lotta | X | 1027 | wholelotta | little | x | 10-27 | reallittle | |
| Other euphemisms are possible, i.e. - mongo, mutha, eensyteensy, ittybitty, nada, zip, zilch ... |
| Frequency (Hz) = n = c/l = ck |
| Wavelength (m) = l = c/n = 1/k |
| Wavenumber (m-1) = k = n/c = 1/l |
| Speed of Light in Vacuum = c0 = 299 792 458 m s-1 (exact) |
| A Frequency and Wavenumber of 0 and a Wavelength of ¥ is called Direct Current. |
| Wait a Second, 0 ´ ¥ = 0/0 = ¼ God, my brain hurts ¼ |
| Electromagnetic Spectrum | ||||
|---|---|---|---|---|
| Frequency | Wavelength | Wavenumber | Band | Energy |
| 3 Hz - 30 Hz | 108 m - 107 m | 10-8 m-1 - 10-7 m-1 | ELF 1, ITU 1 | n/a |
| 30 Hz - 300 Hz | 107 m - 106 m | 10-7 m-1 - 10-6 m-1 | SLF, ELF 2, ITU 2 | n/a |
| 300 Hz - 3 kHz | 106 m - 105 m | 10-6 m-1 - 10-5 m-1 | ULF, ELF 3, ITU 3 | n/a |
| 3 kHz - 30 kHz | 105 m - 104 m | 10-5 m-1 - 10-4 m-1 | VLF, ITU 4, CW | n/a |
| 30 kHz - 300 kHz | 104 m - 103 m | 10-4 m-1 - 10-3 m-1 | LF, ITU 5, CW | n/a |
| 300 kHz - 3 MHz | 1 km - 100 m | 10-3 m-1 - 10-2 m-1 | MF, ITU 6, AM | n/a |
| 3 MHz - 30 MHz | 100 m - 10 m | 10-2 m-1 - 10-1 m-1 | HF, ITU 7, SSB | n/a |
| 30 MHz - 300 MHz | 10 m - 1 m | 10-1 m-1 - 1 m-1 | VHF, ITU 8, FM | n/a |
| Frequency | Wavelength | Wavenumber | Band | Energy |
| 300 MHz - 3 GHz | 1 m - 10 cm | 1 m-1 - 10 m-1 | UHF, ITU 9, FM, TV, Wireless, Microwave | 1 meV - 10 meV |
| 3 GHz - 30 GHz | 10 cm - 1 cm | 10 m-1 - 100 m-1 | SHF, ITU 10, Microwave | 10 meV - 100 meV |
| 30 GHz - 300 GHz | 1 cm - 1 mm | 100 m-1 - 1000 m-1 | EHF, ITU 11, Millimeter | 100 meV - 1 meV |
| 300 GHz - 3 THz | 1 mm - 100 mm | 10 cm-1 - 100 cm-1 | ITU 12, Submillimeter | 1 meV - 10 meV |
| 3 THz - 30 THz | 100 mm - 10 mm | 100 cm-1 - 1000 cm-1 | Far Infrared | 10 meV - 100 meV |
| 30 THz - 300 THz | 10 mm - 1 mm | 1000 cm-1 - 10000 cm-1 | Infrared | 100 meV - 1 eV |
| Frequency | Wavelength | Wavenumber | Band | Energy |
| 3 ´ 1014 Hz - 3 ´ 1015 Hz | 1 mm - 100 nm | 10000 cm-1 - 105 cm-1 | Near Infrared, Visible (Limit at ~ 3 eV), Near Ultraviolet | 1 eV - 10 eV |
| 3 ´ 1015 Hz - 3 ´ 1016 Hz | 100 nm - 10 nm | 10 mm-1 - 100 mm-1 | Far Ultraviolet | 10 eV - 100 eV |
| 3 ´ 1016 Hz - 3 ´ 1017 Hz | 10 nm - 1 nm | 100 mm-1 - 1 nm-1 | Soft X-rays | 100 eV - 1 keV |
| 3 ´ 1017 Hz - 3 ´ 1018 Hz | 1 nm - 1 Å | 1 nm-1 - 10 nm-1 | X-rays | 1 keV - 10 keV |
| 3 ´ 1018 Hz - 3 ´ 1019 Hz | 10-10 m - 10-11 m | 1010 m-1 - 1011 m-1 | Hard X-rays, Soft g Rays | 10 keV - 100 keV |
| 3 ´ 1019 Hz - 3 ´ 1020 Hz | 10-11 m - 10-12 m | 1011 m-1 - 1012 m-1 | Soft g Rays, Hard g Rays (Limit at ~ 511 keV) | 100 keV - 1 MeV |
| 3 ´ 1020 Hz - 3 ´ 1021 Hz | 10-12 m - 10-13 m | 1012 m-1 - 1013 m-1 | Hard "Cosmic" g Rays | 1 MeV - 10 MeV |
| 3 ´ 1021 Hz - 3 ´ 1022 Hz | 10-13 m - 10-14 m | 1013 m-1 - 1014 m-1 | g Rays Produced by Cosmic Rays | 10 MeV - 100 MeV |
| Frequency | Wavelength | Wavenumber | Band | Energy |
Frequencies and Energies greater than this are in the realm of Nuclear Physics, High Energy Physics, Ungodly Physics and Godly Physics, in order of increasing Energy, respectively.
| Microwave Bands | |||
|---|---|---|---|
| Frequency | Wavelength | Wavenumber | Band |
| 1 GHz - 2 GHz | 30 cm - 15 cm | 3.3 m-1 - 6.7 m-1 | L-Band |
| 2 GHz - 4 GHz | 15 cm - 7.5 cm | 6.7 m-1 - 13.3 m-1 | S-Band |
| 4 GHz - 8 GHz | 7.5 cm - 3.7 cm | 13.3 m-1 - 26.7 m-1 | C-Band |
| 8 GHz - 12 GHz | 3.7 cm - 2.5 cm | 26.7 m-1 - 40 m-1 | X-Band |
| 12 GHz - 18 GHz | 2.5 cm - 1.7 cm | 40 m-1 - 60 m-1 | Ku-Band |
| 18 GHz - 27 GHz | 1.7 cm - 1.1 cm | 60 m-1 - 90 m-1 | K-Band |
| 27 GHz - 40 GHz | 1.1 cm- 0.75 cm | 90 m-1 - 133 m-1 | Ka-Band |
SI International System of Units
| SI Defined Units | ||
|---|---|---|
| Quantity | Name | Symbol |
| length (distance) | meter | m |
| mass | kilogram | kg |
| time | second | s |
| temperature | Kelvin | K |
| current | Ampere | A (C s-1) |
| quantity | mole | mol |
| luminosity | candela | cd |
| SI Derived Units | |||
|---|---|---|---|
| Quantity | Name | Symbol | Units |
| frequency | Hertz | Hz | s-1 |
| wavenumber | - | k | m-1 |
| velocity | - | - | m s-1 |
| acceleration | - | - | m s-2 |
| force | Newton | N | kg m s-2 |
| pressure (stress) | Pascal | Pa | N m-2 = kg m-1 s-2 |
| Energy (work, Heat) | Joule | J | N m = kg m2 s-2 = W s |
| momentum (impulse) | Fritz | I | N s = kg m s-1 |
| power | Watt | W | J s-1 = kg m2 s-3 = V A |
| electric charge | Coulomb | C | A s |
| electric potential (emf) | Volt | V | J C-1 = W A-1 = kg m2 s-3 A-1 = J s-1 A-1 |
| resistance | Ohm | W | V A-1 = kg m2 s-3 A-2 = J s-1 A-2 = W A-2 |
| conductance | Siemens | S | A V-1 = W-1 = kg-1 m-2 s3 A2 = J-1 s A2 = A2 W-1 |
| magnetic flux | Weber | Wb | V s = kg m2 s-2 A-1 = J A-1 |
| inductance | Henry | H | Wb A-1 = kg m2 s-2 A-2 = J A-2 |
| capacitance | Farad | F | C V-1 = kg-1 m-2 s4 A2 = J-1 s2 A2 = C2 J-1 |
| electric field strength | - | - | V m-1 = N C-1 |
| electric displacement | - | - | C m-2 |
| magnetic field strength | - | - | A m-1 |
| magnetic flux density | Tesla | T | Wb m-2 = N A-1 m-1 = kg s-2 A-1 |
| plane angle | radian | rad | 2p (circle) |
| solid angle | steradian | sr | 4p (sphere) |
| luminous flux | lumen | lm | cd sr |
| illuminance | lux | lx | lm m-2 |
| SI Accepted Units | |||
|---|---|---|---|
| Quantity | Name | Symbol | Units |
| length | Ångstrom | Å, å | 1 Å = 10-10 m |
| volume | Liter | L, l | 1 L = 10-3 m3 |
| mass | metric ton | t | 1 t = 1000 kg |
| pressure | bar | bar | 1 bar = 105 Pa = 105 N m-2 |
| time | minute | min | 1 min = 60 s |
| time | hour | h | 1 h = 60 min = 3600 s |
| time | day | d | 1 d = 24 h = 1440 min = 86 400 s |
| nautical distance | nautical mile | (nm) | 1 nautical mile = 1852 m |
| nautical speed | knot | (kt) | 1 nautical mile per hour = (1852/3600) m/s |
| plane angle | degree | o | 1o = (p/180) rad |
| plane angle | minute | ' | 1' = (1/60)o = (p/10 800) rad |
| plane angle | second | " | 1" = (1/60)' = (1/3600)o = (p/648 000) rad |
| SI Derived Quantities | ||
|---|---|---|
| Name | Quantity | Units |
| area | square meter | m2 |
| volume | cubic meter | m3 |
| mass density | kilogram per cubic meter | kg/m3 |
| molar concentration | mole per cubic meter | mol/m3 |
| specific volume | cubic meter per kilogram | m3/kg |
| molar mass | kilogram per mole | kg/mol |
| molar volume | cubic meter per mole | m3/mol |
| dynamic viscosity | Pascal second | Pas |
| moment of force | Newton meter, (Joule) | Nm, (J) |
| surface tension | Newton per meter, Joule per meter squared | N/m, J/m2 |
| angular velocity | radian per second | rad/s |
| angular acceleration | radian per second squared | rad/s2 |
| heat flux density, irradiance | Watt per square meter | W/m2 |
| thermal conductivity | Watt per meter Kelvin | W/(mK) |
| heat capacity, entropy | Joule per Kelvin | J/K |
| specific heat capacity, specific entropy | Joule per kilogram Kelvin | J/(kgK) |
| specific energy | Joule per kilogram | J/kg |
| energy density | Joule per cubic meter | J/m3 |
| molar energy | Joule per mole | J/mol |
| molar entropy, molar heat capacity | Joule per mole Kelvin | J/(molK) |
| electric field strength | Volt per meter | V/m |
| electric charge density | Coulomb per cubic meter | C/m3 |
| electric flux density | Coulomb per square meter | C/m2 |
| resistivity | Ohm meter | Wm |
| conductivity | Siemens per meter, (inverse Ohm meter) | S/m, (W-1 m-1) |
| permittivity | Farad per meter | F/m |
| permeability | Henry per meter | H/m, (N/A2) |
| exposure (X-Rays and g-Rays) | Coulomb per kilogram | C/kg |
| radiant intensity | Watt per steradian | W/sr |
| radiance | Watt per square meter steradian | W/(m2sr) |
| luminance | candela per square meter | cd/m2 |
Fundamental Physical Constants
Updated to 1998 CODATA Recommended Values
| Earth Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Standard Atmosphere | atm | 101 325 Pa (exact) |
| Rounded Atmosphere | bar | 100 000 Pa (exact) |
| Standard Acceleration of Gravity | ga, gn | 9.806 65 m s-2 (exact) |
| Astronomical Unit (Earth - Sun) | au | 1.495 978 706 91 (30) ´ 1011 m |
| Universal Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Speed of Light in Vacuum = (m0e0)-1/2 | c, c0 | 299 792 458 m s-1 (exact) |
| Magnetic Constant (Permeability of Vacuum) = 4p ´ 10-7 N A-2 (4p ´ 10-7 H m-1) = 1/e0c2 | m0 | 12.566 370 614 ¼ ´ 10-7 N A-2 (H m-1) |
| Electric Constant (Permittivity of Vacuum) = 1/m0c2 | e0 | 8.854 187 817 ¼ ´ 10-12 F m-1 |
| Characteristic Impedance of Vacuum = (m0/e0)1/2 = m0c = 1/e0c | Z0 | 376.730 313 461 ¼ W |
| Newtonian Constant of Gravitation | G | 6.673 (10) ´ 10-11 m3 kg-1 s-2 |
| Newtonian Constant of Gravitation | G/ | 6.707 (10) ´ 10-39 (GeV/c2)-2 |
| electron Volt (in Joules) = {e/C} J | eV | 1.602 176 462 (63) ´ 10-19 J |
| (unified) atomic mass unit = m(12C)/12 = 10-3 kg mol-1/NA | u | 1.660 538 73 (13) ´ 10-27 kg = 1 Dalton (Da) |
| Planck Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Planck Constant (in Joules) | h | 6.626 068 76 (52) ´ 10-34 J s (I m) |
| Planck Constant = h/{e} (in electron Volts) | h/{e} | 4.135 667 27 (16) ´ 10-15 eV s |
| Reduced Planck Constant = h/2p (in Joules) | 1.054 571 596 (82) ´ 10-34 J s (I m) | |
| Reduced Planck Constant = h/2p{e} (in electron Volts) | 6.582 118 89 (26) ´ 10-16 eV s | |
| Planck Mass = ( | mP | 2.176 7 (16) ´ 10-8 kg |
| Planck Length = | lP | 1.616 0 (12) ´ 10-35 m |
| Planck Time = lP/c = ( | tP | 5.390 6 (40) ´ 10-44 s |
| Electromagnetic Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Electronic Charge Quantum = e | e | 1.602 176 462 (63) ´ 10-19 C |
| Quantized Electronic Charge = e/h | e/h | 2.417 989 491 (95) ´ 1014 A J-1 |
| Magnetic Flux Quantum = h/2e | F0 | 2.067 833 636 (81) ´ 10-15 Wb |
| Conductance Quantum = 2e2/h | G0 | 7.748 091 696 (28) ´ 10-5 S |
| Inverse Conductance Quantum = h/2e2 | G0-1 | 12 906.403 786 (95) W |
| Josephson Constant = 2e/h | KJ | 0.483 597 898 (19) ´ 1015 Hz V-1 |
| Josephson Constant (conventional value) | KJ-90 | 483 597.9 GHz V-1 (exact) |
| von Klitzing Constant = h/e2 = m0c/2a | RK | 25 812.807 592 (95) W |
| von Klitzing Constant (conventional value) | RK-90 | 25 812.807 W (exact) |
| Mental Note : Conventional values are the internationally adopted exact values, used for realizing representations of the Volt using the Josephson effect, and the Ohm using the quantum Hall effect (QHE). | ||
| Bohr Magneton | ||
|---|---|---|
| Constant | Symbol | Value |
| Bohr Magneton = e | mB | 9.274 008 99 (37) ´ 10-24 J T-1 |
| Bohr Magneton = mB/{e} (in electron Volts) | mB/e | 5.788 381 749 (43) ´ 10-5 eV T-1 |
| Bohr Magneton = mB/h (in Hertz) | mB/h | 1.399 624 624 (56) ´ 1010 Hz T-1 |
| Bohr Magneton = mB/hc (in wavenumbers) | mB/hc | 46.686 452 1 (19) m-1 T-1 |
| Bohr Magneton = mB/k (in Kelvins) | mB/k | 0.671 713 1 (12) K T-1 |
| Nuclear Magneton | ||
|---|---|---|
| Constant | Symbol | Value |
| Nuclear Magneton = e | mN | 5.050 783 17 (20) ´ 10-27 J T-1 |
| Nuclear Magneton = mN/{e} (in electron Volts) | mN/e | 3.152 451 238 (24) ´ 10-8 eV T-1 |
| Nuclear Magneton = mN/h (in Hertz) | mN/h | 7.622 593 964 (31) MHz T-1 |
| Nuclear Magneton = mN/hc (in wavenumbers) | mN/hc | 2.542 623 66 (10) ´ 10-2 m-1 T-1 |
| Nuclear Magneton = mN/k (in Kelvins) | mN/k | 3.658 263 8 (64) ´ 10-4 K T-1 |
| (Inverse) Fine Structure Constant | ||
|---|---|---|
| Constant | Symbol | Value |
| Fine Structure Constant = m0ce2/2h = e2/2he0c | a | 7.297 352 533 (27) ´ 10-3 |
| Inverse Fine Structure Constant = 2h/e2m0c = e0c2h/e2 | 1/a = a-1 | 137.035 999 76 (50) |
| Rydberg Constant | ||
|---|---|---|
| Constant | Symbol | Value |
| Rydberg Constant = meca2/2h = Eh/2hc | R¥ | 10 973 731.568 549 (83) m-1 |
| Rydberg Constant = R¥c (in Hertz) | R¥c | 3.289 841 960 368 (25) ´ 1015 Hz |
| Rydberg Constant = R¥hc (in Joules) | R¥hc | 2.179 871 90 (17) ´ 10-18 J |
| Rydberg Constant = R¥hc/{e} (in electron Volts) | R¥hc/{e} | 13.605 691 72 (53) eV |
| Physical Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Bohr Radius = a/4pR¥ = 4pe0 | a0 | 0.529 177 208 3 (19) ´ 10-10 m |
| Hartree Energy = e2/4pe0a0 = 2R¥hc = a2mec2 = | Eh | 4.359 743 81 (34) ´ 10-18 J |
| Hartree Energy = Eh/{e} (in electron Volts) | Eh/{e} | 27.211 383 4 (11) eV |
| Quantum of Circulation = h/2me | h/2me | 3.636 947 516 (27) ´ 10-4 m2 s-1 |
| Quanta of Circulation = h/me | h/me | 7.273 895 032 (53) ´ 10-4 m2 s-1 |
| Chemical Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Avogadro's Number (Avogadro Constant) | NA, L | 6.022 141 99 (47) ´ 1023 mol-1 |
| Atomic Mass Constant = m(12C)/12 = 10-3 kg mol-1/NA | mu | 1.660 538 73 (13) ´ 10-27 kg = 1 Dalton (Da) |
| Atomic Mass Constant = muc2 (in Joules) | muc2 | 1.492 417 78 (12) ´ 10-10 J |
| Atomic Mass Constant = muc2/{e} (in electron Volts) | muc2/{e} | 931.494 013 (37) MeV |
| Faraday Constant = NAe | F | 96 485.341 5 (39) C mol-1 |
| Faraday Constant = NAe (conventional value) | F | 96 485.343 2 (76) C mol-1 |
| Molar Planck Constant = NAh | NAh | 3.990 312 689 (30) ´ 10-10 J s mol-1 |
| Molar Planck Constant = NAhc | NAhc | 0.119 626 564 92 (91) J m mol-1 |
| Molar Gas Constant | R | 8.314 472 (15) J mol-1 K-1 |
| Molar Volume = RT / p (Ideal Gas at T = 273.15 K, p = 101 325 Pa - Standard Atmosphere) | Vm | 22 413.996 (39) cm3 mol-1 ( p = 101 325 Pa) |
| Molar Volume = RT / p (Ideal Gas at T = 273.15 K, p = 100 000 Pa - Rounded Atmosphere) | Vm | 22 710.981 (40) cm3 mol-1 ( p = 100 000 Pa) |
| Loschmidt Constant = NA/Vm | n0 | 2.686 777 5 (47) ´ 1025 m-3 |
| Boltzmann Constant | ||
|---|---|---|
| Constant | Symbol | Value |
| Boltzmann Constant = R/NA | k, kB | 1.380 650 3 (24) ´ 10-23 J K-1 |
| Boltzmann Constant = k/{e} (in electron Volts) | k/{e} | 8.617 342 (15) ´ 10-5 eV K-1 |
| Boltzmann Constant = k/h (in Hertz) | k/h | 2.083 664 4 (36) ´ 1010 Hz K-1 |
| Boltzmann Constant = k/hc (in wavenumbers) | k/hc | 69.503 56 (12) m-1 K-1 |
| Physicochemical Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Stefan-Boltzmann Constant = (p2/60)k4/ | s | 5.670 400 (40) ´ 10-8 W m-2 K-4 |
| First Radiation Constant = 2phc2 | c1 | 3.741 771 07 (93) ´ 10-16 W m2 |
| First Radiation Constant (Spectral Radiance) = 2hc2 | c1L | 1.191 042 722 (29) ´ 10-16 W m2 sr-1 |
| Second Radiation Constant = hc/k | c2 | 0.014 387 752 (25) m K |
| Wien Displacement Law Constant = lmaxT = c2 / 4.965 114 231 ¼ | b | 2.897 768 6 (51) m K |
| Sackur-Tetrode Constant (absolute entropy constant) = 5/2 + ln[(2pmu kT1 / h2)3/2 kT1 / p0], T1 = 1 K, p0 = 101.325 kPa - Standard Atmosphere | - | 1.164 867 8 (44) |
| Sackur-Tetrode Constant (absolute entropy constant) = 5/2 + ln[(2pmu kT1 / h2)3/2 kT1 / p0], T1 = 1 K, p0 = 100 kPa - Rounded Atmosphere | S0/R | 1.151 704 8 (44) |
| Mental Note : The entropy of an ideal monoatomic gas of relative atomic mass Ar is given by : S = S0 + 3/2 R ln Ar R ln ( p / p0) + 5/2 R ln (T / K). | ||
| Electron Constants | ||||||||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Constant | Symbol | Value | ||||||||||||||||||||||||||||||||||||
| Electron Mass | me | 9.109 381 88 (72) ´ 10-31 kg | ||||||||||||||||||||||||||||||||||||
| Electron Mass (in atomic mass units) | me | 5.485 799 110 (12) ´ 10-4 u (amu) | ||||||||||||||||||||||||||||||||||||
| Electron Mass = mec2 (in Joules) | mec2 | 8.187 104 14 (64) ´ 10-14 J | ||||||||||||||||||||||||||||||||||||
| Electron Mass = mec2/{e} (in electron Volts) | mec2/{e} | 0.510 998 902 (21) MeV | ||||||||||||||||||||||||||||||||||||
| Electron - Proton Mass Ratio = me/mp | me/mp | 5.446 170 232 (12) ´ 10-4 | ||||||||||||||||||||||||||||||||||||
| Electron - Neutron Mass Ratio = me/mn | me/mn | 5.438 673 462 (12) ´ 10-4 | ||||||||||||||||||||||||||||||||||||
| Electron - Deuteron Mass Ratio = me/md | me/md | 2.724 437 117 0 (58) ´ 10-4 | ||||||||||||||||||||||||||||||||||||
| Electron Charge to Mass Ratio = e/me | e/me | 1.758 820 174 (71) ´ 1011 C kg-1 | ||||||||||||||||||||||||||||||||||||
| Electron Molar Mass = NAme | M(e), Me | 5.485 799 110 (12) ´ 10-7 kg mol-1 | ||||||||||||||||||||||||||||||||||||
| Electron Compton Wavelength = h/mec | lC(e) | 2.426 310 215 (18) ´ 10-12 m | ||||||||||||||||||||||||||||||||||||
Electron Compton Wavelength = lC(e)/2p = aa0 = a2/4pR¥ | 3.861 592 642 (28) ´ 10-13 m | Electron Classical Radius = a2 a0 | re | 2.817 940 285 (31) ´ 10-15 m | Thomson Cross Section = (8p/3)re2 | se | 0.665 245 854 (15) ´ 10-28 m2 | Electron Magnetic Moment | me | 928.476 362 (37) ´ 10-26 J T-1 | Electron Magnetic Moment = me/mB (in Bohr magnetons) | me/mB | 1.001 159 652 186 9 (41) | Electron Magnetic Moment = me/mN (in Nuclear magnetons) | me/mN | 1 838.281 966 0 (39) | Electron Magnetic Moment Anomaly = me/mB 1 | ae | 1.159 652 186 9 (41) ´ 10-3 | Electron g-factor = 2(1 + ae) | ge | 2.002 319 304 373 7 (82) | Electron - Proton Magnetic Moment Ratio = me/mp | me/mp | 658.210 687 5 (66) | Electron - Neutron Magnetic Moment Ratio = me/mn | me/mn | 960.920 50 (23) | Electron - Deuteron Magnetic Moment Ratio = me/md | me/md | 2 143.923 498 (23) | Electron Gyromagnetic Ratio = 2|me|/ | ge | 1.760 859 794 (71) ´ 1011 s-1 T-1 | Electron Gyromagnetic Ratio = ge/2p = 2|me|/h | ge/2p | 28 024.954 0 (11) MHz T-1 | | |
| Proton Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Proton Mass | mp | 1.672 621 58 (13) ´ 10-27 kg |
| Proton Mass (in atomic mass units) | mp | 1.007 276 466 88 (13) u (amu) |
| Proton Mass = mpc2 (in Joules) | mpc2 | 1.503 277 31 (12) ´ 10-10 J |
| Proton Mass = mpc2/{e} (in electron Volts) | mpc2/{e} | 938.271 998 (38) MeV |
| Proton - Electron Mass Ratio = mp/me | mp/me | 1836.152 667 5 (39) |
| Proton - Neutron Mass Ratio = mp/mn | mp/mn | 0.998 623 478 55 (58) |
| Proton Charge to Mass Ratio = e/mp | e/mp | 9.578 834 08 (38) ´ 107 C kg-1 |
| Proton Molar Mass = NAmp | M(p), Mp | 1.007 276 466 88 (13) ´ 10-3 kg mol-1 |
| Proton Compton Wavelength = h/mpc | lC(p) | 1.321 409 847 (10) ´ 10-15 m |
| Proton Compton Wavelength = lC(p)/2p | 2.103 089 089 (16) ´ 10-16 m | |
| Proton Magnetic Moment | mp | 1.410 606 633 (58) ´ 10-26 J T-1 |
| Proton Magnetic Moment = mp/mB (in Bohr magnetons) | mp/mB | 1.521 032 203 (15) ´ 10-3 |
| Proton Magnetic Moment = mp/mN (in Nuclear magnetons) | mp/mN | 2.792 847 337 (29) |
| Proton - Neutron Magnetic Moment Ratio = mp/mn | mp/mn | 1.459 898 05 (34) |
| Proton g-factor = 2mp/mN | gp | 5.585 694 675 (57) |
| Proton Gyromagnetic Ratio = 2|mp|/ | gp | 2.675 222 12 (11) ´ 108 s-1 T-1 |
| Proton Gyromagnetic Ratio = gp/2p = 2|mp|/h | gp/2p | 42.577 482 5 (18) MHz T-1 |
| Neutron Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Neutron Mass | mn | 1.674 927 16 (13) ´ 10-27 kg |
| Neutron Mass (in atomic mass units) | mn | 1.008 664 915 78 (55) u (amu) |
| Neutron Mass = mnc2 (in Joules) | mnc2 | 1.505 349 46 (12) ´ 10-10 J |
| Neutron Mass = mnc2/{e} (in electron Volts) | mnc2/{e} | 939.565 330 (38) MeV |
| Neutron - Electron Mass Ratio = mn/me | mn/me | 1838.683 655 0 (40) |
| Neutron - Proton Mass Ratio = mn/mp | mn/mp | 1.001 378 418 87 (58) |
| Neutron Molar Mass = NAmn | M(n), Mn | 1.008 664 915 78 (55) ´ 10-3 kg mol-1 |
| Neutron Compton Wavelength = h/mnc | lC(n) | 1.319 590 898 (10) ´ 10-15 m |
| Neutron Compton Wavelength = lC(n)/2p | 2.100 194 142 (16) ´ 10-16 m | |
| Neutron Magnetic Moment | mn | 0.966 236 40 (23) ´ 10-26 J T-1 |
| Neutron Magnetic Moment = mn/mB (in Bohr magnetons) | mn/mB | 1.041 875 63 (25) ´ 10-3 |
| Neutron Magnetic Moment = mn/mN (in Nuclear magnetons) | mn/mN | 1.913 042 72 (45) |
| Neutron - Electron Magnetic Moment Ratio = mn/me | mn/mB | 1.040 668 82 (25) ´ 10-3 |
| Neutron - Proton Magnetic Moment Ratio = mn/mp | mn/mp | 0.684 979 34 (16) |
| Neutron g-factor = 2mn/mN | gn | 3.826 085 45 (90) |
| Neutron Gyromagnetic Ratio = 2|mn|/ | gn | 1.832 471 88 (44) ´ 108 s-1 T-1 |
| Neutron Gyromagnetic Ratio = gn/2p = 2|mn|/h | gn/2p | 29.164 695 8 (70) MHz T-1 |
| Deuteron Constants | ||
|---|---|---|
| Constant | Symbol | Value |
| Deuteron Mass | md | 3.343 583 09 (26) ´ 10-27 kg |
| Deuteron Mass (in atomic mass units) | md | 2.013 553 212 71 (35) u (amu) |
| Deuteron Mass = mdc2 (in Joules) | mdc2 | 3.005 062 62 (24) ´ 10-10 J |
| Deuteron Mass = mdc2/{e} (in electron Volts) | mdc2/{e} | 1 875.612 762 (75) MeV |
| Deuteron - Electron Mass Ratio = md/me | md/me | 3 670.482 955 0 (78) |
| Deuteron - Proton Mass Ratio = md/mp | md/mp | 1.999 007 500 83 (41) |
| Deuteron Molar Mass = NAmd | M(d), Md | 2.013 553 212 71 (35) ´ 10-3 kg mol-1 |
| Deuteron Magnetic Moment | md | 0.433 073 457 (18) ´ 10-26 J T-1 |
| Deuteron Magnetic Moment = md/mB (in Bohr magnetons) | md/mB | 0.466 975 4556 (50) ´ 10-3 |
| Deuteron Magnetic Moment = md/mN (in Nuclear magnetons) | md/mN | 0.857 438 2284 (94) |
| Deuteron - Electron Magnetic Moment Ratio = md/me | md/mB | 4.664 345 537 (50) ´ 10-4 |
| Deuteron - Proton Magnetic Moment Ratio = md/mp | md/mp | 0.307 012 2083 (45) |
| Deuteron - Neutron Magnetic Moment Ratio = md/mn | md/mn | 0.448 206 52 (11) |
| Energy Equivalence Factors |
|---|
| E = mc2 = hc/l = hn = kT |
| Next | Energy Equivalence I | Previous |
|---|---|---|
| Units | J (Joule) | kg (kilogram) |
| 1 J (Joule) = | 1 J (Joule) | 1.112 650 056 ´ 10-17 kg |
| 1 kg (kilogram) = | 8.987 551 787 ´ 1016 J | 1 kg (kilogram) |
| 1 m-1 (wavenumber) = | 1.986 445 44 (16) ´ 10-25 J | 2.210 218 63 (17) ´ 10-42 kg |
| 1 Hz (Hertz) = | 6.626 068 76 (52) ´ 10-34 J | 7.372 495 78 (58) ´ 10-51 kg |
| 1 K (Kelvin) = | 1.380 650 3 (24) ´ 10-23 J | 1.536 180 7 (27) ´ 10-40 kg |
| 1 eV (electron Volt) = | 1.602 176 462 (63) ´ 10-19 J | 1.782 661 731 (70) ´ 10-36 kg |
| 1 u (atomic mass unit) = | 1.492 417 78 (12) ´ 10-10 J | 1.660 538 73 (13) ´ 10-27 kg |
| 1 Hartree (atomic energy unit) = | 4.359 743 81 (34) ´ 10-18 J | 4.850 869 19 (38) ´ 10-35 kg |
| Next | Energy Equivalence II | Previous |
|---|---|---|
| Units | m-1 (wavenumber) | Hz (Hertz) |
| 1 J (Joule) = | 5.034 117 62 (39) ´ 1024 m-1 | 1.509 190 50 (12) ´ 1033 Hz |
| 1 kg (kilogram) = | 4.524 439 29 (35) ´ 1041 m-1 | 1.356 392 77 (11) ´ 1050 Hz |
| 1 m-1 (wavenumber) = | 1 m-1 (wavenumber) | 299 792 458 Hz |
| 1 Hz (Hertz) = | 3.335 640 952 ´ 10-9 m-1 | 1 Hz (Hertz) |
| 1 K (Kelvin) = | 69.503 56 (12) m-1 | 2.083 664 4 (36) ´ 1010 Hz |
| 1 eV (electron Volt) = | 806 544.77 (32) m-1 | 2.417 989 491 (95) ´ 1014 Hz |
| 1 u (atomic mass unit) = | 7.513 006 658 (57) ´ 1014 m-1 | 2.252 342 733 (17) ´ 1023 Hz |
| 1 Hartree (atomic energy unit) = | 21 947 463.137 10 (17) m-1 | 6.579 683 920 735 (50) ´ 1015 Hz |
| Next | Energy Equivalence III | Previous |
|---|---|---|
| Units | K (Kelvin) | eV (electron Volt) |
| 1 J (Joule) = | 7.242 964 (13) ´ 1022 K | 6.241 509 74 (24) ´ 1018 eV |
| 1 kg (kilogram) = | 6.509 651 (11) ´ 1039 K | 5.609 589 21 (22) ´ 1035 eV |
| 1 m-1 (wavenumber) = | 0.014 387 752 (25) K | 1.239 841 857 (49) ´ 10-6 eV |
| 1 Hz (Hertz) = | 4.799 237 4 (84) ´ 10-11 K | 4.135 667 27 (16) ´ 10-15 eV |
| 1 K (Kelvin) = | 1 K (Kelvin) | 8.617 342 (15) ´ 10-5 eV |
| 1 eV (electron Volt) = | 11 604.506 K | 1 eV (electron Volt) |
| 1 u (atomic mass unit) = | 1.080 952 8 (19) ´ 1013 K | 931.494 013 (37) ´ 106 eV |
| 1 Hartree (atomic energy unit) = | 3.157 746 5 (55) ´ 105 K | 27.211 383 4 (11) eV |
| Next | Energy Equivalence IV | Previous |
|---|---|---|
| Units | u (atomic mass unit) | Hartree (atomic energy unit) |
| 1 J (Joule) = | 6.700 536 62 (53) ´ 109 u | 2.293 712 76 (18) ´ 1017 Hartree |
| 1 kg (kilogram) = | 6.022 141 99 (47) ´ 1026 u | 2.061 486 22 (16) ´ 1034 Hartree |
| 1 m-1 (wavenumber) = | 1.331 025 042 (10) ´ 10-15 u | 4.556 335 252 750 (35) ´ 10-8 Hartree |
| 1 Hz (Hertz) = | 4.439 821 637 (34) ´ 10-24 u | 1.519 829 846 003 (12) ´ 10-16 Hartree |
| 1 K (Kelvin) = | 9.251 098 (16) ´ 10-14 u | 3.166 815 3 (55) ´ 10-6 Hartree |
| 1 eV (electron Volt) = | 1.073 544 206 (43) ´ 10-9 u | 0.036 749 326 0 (14) Hartree |
| 1 u (atomic mass unit) = | 1 u (atomic mass unit) | 3.423 177 709 (26) ´ 107 Hartree |
| 1 Hartree (atomic energy unit) = | 2.921 262 304 (22) ´ 10-8 u | 1 Hartree (atomic energy unit) |
| Energy Conversion Factors |
|---|
| E = mc2 = hc/l = hn = kT |
| Next | Energy Conversion I | Previous |
|---|---|---|
| Units | J (Joule) | kg (kilogram) |
| 1 J (Joule) ´ factor = energy equivalent = | 1 J (Joule) ´ 1 = 1 J (Joule) | 1 J (Joule) ´ {1/c2} = 1.112 650 056 ´ 10-17 kg |
| 1 kg (kilogram) ´ factor = energy equivalent = | 1 kg (kilogram) ´ {c2} = 8.987 551 787 ´ 1016 J | 1 kg (kilogram) ´ 1 = 1 kg (kilogram) |
| 1 m-1 (wavenumber) ´ factor = energy equivalent = | 1 m-1 (wavenumber) ´ {hc} = 1.986 445 44 (16) ´ 10-25 J | 1 m-1 (wavenumber) ´ {h/c} = 2.210 218 63 (17) ´ 10-42 kg |
| 1 Hz (Hertz) ´ factor = energy equivalent = | 1 Hz (Hertz) ´ {h} = 6.626 068 76 (52) ´ 10-34 J | 1 Hz (Hertz) ´ {h/c2} = 7.372 495 78 (58) ´ 10-51 kg |
| 1 K (Kelvin) ´ factor = energy equivalent = | 1 K (Kelvin) ´ {k} = 1.380 650 3 (24) ´ 10-23 J | 1 K (Kelvin) ´ {k/c2} = 1.536 180 7 (27) ´ 10-40 kg |
| 1 eV (electron Volt) ´ factor = energy equivalent = | 1 eV (electron Volt) ´ {e} = 1.602 176 462 (63) ´ 10-19 J | 1 eV (electron Volt) ´ {e/c2} = 1.782 661 731 (70) ´ 10-36 kg |
| 1 u (atomic mass unit) ´ factor = energy equivalent = | 1 u (atomic mass unit) ´ {muc2} = 1.492 417 78 (12) ´ 10-10 J | 1 u (atomic mass unit) ´ {mu} = 1.660 538 73 (13) ´ 10-27 kg |
| 1 Hartree (atomic energy unit) ´ factor = energy equivalent = | 1 Hartree ´ {2R¥hc} = 4.359 743 81 (34) ´ 10-18 J | 1 Hartree ´ {2R¥h/c} = 4.850 869 19 (38) ´ 10-35 kg |
| Next | Energy Conversion II | Previous |
|---|---|---|
| Units | m-1 (wavenumber) | Hz (Hertz) |
| 1 J (Joule) ´ factor = energy equivalent = | 1 J (Joule) ´ {1/hc} = 5.034 117 62 (39) ´ 1024 m-1 | 1 J (Joule) ´ {1/h} = 1.509 190 50 (12) ´ 1033 Hz |
| 1 kg (kilogram) ´ factor = energy equivalent = | 1 kg (kilogram) ´ {c/h} = 4.524 439 29 (35) ´ 1041 m-1 | 1 kg (kilogram) ´ {c2/h} = 1.356 392 77 (11) ´ 1050 Hz |
| 1 m-1 (wavenumber) ´ factor = energy equivalent = | 1 m-1 (wavenumber) ´ 1 = 1 m-1 (wavenumber) | 1 m-1 (wavenumber) ´ {c} = 299 792 458 Hz |
| 1 Hz (Hertz) ´ factor = energy equivalent = | 1 Hz (Hertz) ´ {1/c} = 3.335 640 952 ´ 10-9 m-1 | 1 Hz (Hertz) ´ 1 = 1 Hz (Hertz) |
| 1 K (Kelvin) ´ factor = energy equivalent = | 1 K (Kelvin) ´ {k/hc} = 69.503 56 (12) m-1 | 1 K (Kelvin) ´ {k/h} = 2.083 664 4 (36) ´ 1010 Hz |
| 1 eV (electron Volt) ´ factor = energy equivalent = | 1 eV (electron Volt) ´ {e/hc} = 806 544.77 (32) m-1 | 1 eV (electron Volt) ´ {e/h} = 2.417 989 491 (95) ´ 1014 Hz |
| 1 u (atomic mass unit) ´ factor = energy equivalent = | 1 u (atomic mass unit) ´ {muc/h} = 7.513 006 658 (57) ´ 1014 m-1 | 1 u (atomic mass unit) ´ {muc2/h} = 2.252 342 733 (17) ´ 1023 Hz |
| 1 Hartree (atomic energy unit) ´ factor = energy equivalent = | 1 Hartree ´ {2R¥} = 21 947 463.137 10 (17) m-1 | 1 Hartree ´ {2R¥c} = 6.579 683 920 735 (50) ´ 1015 Hz |
| Next | Energy Conversion III | Previous |
|---|---|---|
| Units | K (Kelvin) | eV (electron Volt) |
| 1 J (Joule) ´ factor = energy equivalent = | 1 J (Joule) ´ {1/k} = 7.242 964 (13) ´ 1022 K | 1 J (Joule) ´ {1/e} = 6.241 509 74 (24) ´ 1018 eV |
| 1 kg (kilogram) ´ factor = energy equivalent = | 1 kg (kilogram) ´ {c2/k} = 6.509 651 (11) ´ 1039 K | 1 kg (kilogram) ´ {c2/e} = 5.609 589 21 (22) ´ 1035 eV |
| 1 m-1 (wavenumber) ´ factor = energy equivalent = | 1 m-1 (wavenumber) ´ {hc/k} = 0.014 387 752 (25) K | 1 m-1 (wavenumber) ´ {hc/e} = 1.239 841 857 (49) ´ 10-6 eV |
| 1 Hz (Hertz) ´ factor = energy equivalent = | 1 Hz (Hertz) ´ {h/k} = 4.799 237 4 (84) ´ 10-11 K | 1 Hz (Hertz) ´ {h/e} = 4.135 667 27 (16) ´ 10-15 eV |
| 1 K (Kelvin) ´ factor = energy equivalent = | 1 K (Kelvin) ´ 1 = 1 K (Kelvin) | 1 K (Kelvin) ´ {k/e} = 8.617 342 (15) ´ 10-5 eV |
| 1 eV (electron Volt) ´ factor = energy equivalent = | 1 eV (electron Volt) ´ {e/k} = 11 604.506 K | 1 eV (electron Volt) ´ 1 = 1 eV (electron Volt) |
| 1 u (atomic mass unit) ´ factor = energy equivalent = | 1 u (atomic mass unit) ´ {muc2/k} = 1.080 952 8 (19) ´ 1013 K | 1 u (atomic mass unit) ´ {muc2/e} = 931.494 013 (37) ´ 106 eV |
| 1 Hartree (atomic energy unit) ´ factor = energy equivalent = | 1 Hartree ´ {2R¥hc/k} = 3.157 746 5 (55) ´ 105 K | 1 Hartree ´ {2R¥hc/e} = 27.211 383 4 (11) eV |
| Next | Energy Conversion IV | Previous |
|---|---|---|
| Units | u (atomic mass unit) | Hartree (atomic energy unit) |
| 1 J (Joule) ´ factor = energy equivalent = | 1 J (Joule) ´ {1/muc2} = 6.700 536 62 (53) ´ 109 u | 1 J (Joule) ´ {1/2R¥hc} = 2.293 712 76 (18) ´ 1017 Hartree |
| 1 kg (kilogram) ´ factor = energy equivalent = | 1 kg (kilogram) ´ {1/mu} = 6.022 141 99 (47) ´ 1026 u | 1 kg (kilogram) ´ {c/2R¥h} = 2.061 486 22 (16) ´ 1034 Hartree |
| 1 m-1 (wavenumber) ´ factor = energy equivalent = | 1 m-1 (wavenumber) ´ {h/muc} = 1.331 025 042 (10) ´ 10-15 u | 1 m-1 (wavenumber) ´ {1/2R¥} = 4.556 335 252 750 (35) ´ 10-8 Hartree |
| 1 Hz (Hertz) ´ factor = energy equivalent = | 1 Hz (Hertz) ´ {h/muc2} = 4.439 821 637 (34) ´ 10-24 u | 1 Hz (Hertz) ´ {1/2R¥c} = 1.519 829 846 003 (12) ´ 10-16 Hartree |
| 1 K (Kelvin) ´ factor = energy equivalent = | 1 K (Kelvin) ´ {k/muc2} = 9.251 098 (16) ´ 10-14 u | 1 K (Kelvin) ´ {k/2R¥hc} = 3.166 815 3 (55) ´ 10-6 Hartree |
| 1 eV (electron Volt) ´ factor = energy equivalent = | 1 eV (electron Volt) ´ {e/muc2} = 1.073 544 206 (43) ´ 10-9 u | 1 eV (electron Volt) ´ {e/2R¥hc} = 0.036 749 326 0 (14) Hartree |
| 1 u (atomic mass unit) ´ factor = energy equivalent = | 1 u (atomic mass unit) ´ 1 = 1 u (atomic mass unit) | 1 u (atomic mass unit) ´ {muc/2R¥h} = 3.423 177 709 (26) ´ 107 Hartree |
| 1 Hartree (atomic energy unit) ´ factor = energy equivalent = | 1 Hartree ´ {2R¥h/muc} = 2.921 262 304 (22) ´ 10-8 u | 1 Hartree (atomic energy unit) ´ 1 = 1 Hartree (atomic energy unit) |
| Next | Natural Units (n.u.) | Previous | |
| Unit | Description | Symbol | Value |
|---|---|---|---|
| n.u. of velocity | Speed of Light in vacuum | c, c0 | 299 792 458 m s-1 (exact) |
| n.u. of action | Reduced Planck Constant = | 1.054 571 596 (82) ´ 10-34 J s (I m) | |
| n.u. of mass | Electron Rest Mass (in kilograms) | me | 9.109 381 88 (72) ´ 10-31 kg |
| n.u. of energy | electron energy equivalent (in Joules) | mec2 | 8.187 104 14 (64) ´ 10-14 J |
| n.u. of energy | electron energy equivalent (in electron Volts) | mec2/{e} | 0.510 998 902 (21) MeV |
| n.u. of momentum | electron momentum equivalent | mec | 2.730 923 98 (21) ´ 10-22 I (Fritz, N s, kg m s-1) |
| n.u. of momentum | electron momentum equivalent (in electron Volts/c) | mec/{e} | 0.510 998 902 (21) MeV/c |
| n.u. of length | electron Compton wavelength = | 386.159 264 2 (28) ´ 10-15 m | |
| n.u. of time | electronic transition equivalent | 1.288 088 655 5 (95) ´ 10-21 s | |
| Next | Atomic Units (a.u.) | Previous |
| Unit | Symbol | Value |
|---|---|---|
| a.u. of mass (Electron Rest Mass) | me | 9.109 381 88 (72) ´ 10-31 kg |
| a.u. of charge (Electronic Charge) | e | 1.602 176 462 (63) ´ 10-19 C |
| a.u. of action (Reduced Planck Constant) | 1.054 571 596 (82) ´ 10-34 J s (I m) | |
| a.u. of length (Bohr Radius) | a0 = 4pe0 | 0.529 177 208 3 (19) ´ 10-10 m |
| a.u. of energy (Hartree Energy) | Eh = e2/4pe0a0 = 2R¥hc = a2mec2 = | 4.359 743 81 (34) ´ 10-18 J |
| a.u. of time | 2.418 884 326 500 (18) ´ 10-17 s | |
| a.u. of velocity | a0Eh/ | 2.187 691 252 9 (80) ´ 106 m s-1 |
| c/a.u. of velocity | c | 137.035 989 5 (61) |
| a.u. of force | Eh/a0 | 8.238 721 81 (64) ´ 10-8 N |
| a.u. of momemtum | 1.992 851 51 (16) ´ 10-24 I (Fritz, N s, kg m s-1) | |
| a.u. of current | eEh/ | 6.623 617 53 (26) ´ 10-3 A |
| a.u. of charge density | ea03 | 1.081 202 285 (43) ´ 1012 C m-3 |
| a.u. of electric potential | Eh/e | 27.211 383 4 (11) V |
| a.u. of electric field | Eh/ea0 | 5.142 206 24 (20) ´ 1011 V m-1 |
| a.u. of electric field gradient | Eh/ea02 | 9.717 361 53 (39) ´ 1021 V m-2 |
| a.u. of electric dipole moment | ea0 | 8.478 352 67 (33) ´ 10-30 C m |
| a.u. of electric quadrupole moment | ea02 | 4.486 551 00 (18) ´ 10-40 C m2 |
| a.u. of polarizability | e2a02/Eh | 1.648 777 251 (18) ´ 10-41 C2 m2 J-1 |
| a.u. of first hyperpolarizability | e3a03/Eh2 | 3.206 361 57 (14) ´ 10-53 C3 m3 J-2 |
| a.u. of second hyperpolarizability | e4a04/Eh3 | 6.235 381 12 (51) ´ 10-65 C4 m4 J-3 |
| a.u. of magnetic flux density | 2.350 517 349 (94) ´ 105 T | |
| a.u. of magentic dipole moment | Eh/me = 2mB | 1.854 801 799 (75) ´ 10-23 J T-1 |
| a.u. of magnetizability | e2a02/me | 7.891 036 41 (14) ´ 10-29 J T-1 |
| a.u. of permittivity (107/c2) | e2/a0Eh | 1.112 650 056 ¼ ´ 10-10 F m-1 |
| A Note on Notation : Units in theoretical calculations are usually renormalized to |
| Next | Other (SI Derived) Units | Previous | |
|---|---|---|---|
| Quantity | Unit | Symbol | Value in SI Units |
| Force (Newton) | dyne | dyn | 10-5 N |
| Pressure (Pascal) | Rounded Atmosphere | bar | 100 000 Pa |
| Standard Atmosphere | atm | 101 325 Pa | |
| torr (mmHg) | Torr | 133 322 Pa | |
| Energy (Joule) | erg | erg | 10-7 J |
| thermochemical calorie | calth | 4.184 J | |
| Magnetic Flux Density | Gauss (gauss) | G | 10-4 T |
| Electric Dipole Moment | Debye (debye) | D | 3.335 64 ´ 10-30 C m |
| Dynamic Viscosity | Poise (poise) | P | 10-1 N s m-2, (10-1 Pa s) |
| Kinematic Viscosity | Stokes (stokes) | St | 10-4 m2 s-1 |
Symbols and Terminology of Condensed Matter Physics
Physical and Chemical Quantities
| Space and Time | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| cartesian space coordinates | x, y, z | - | m |
| spherical space coordinates | r, q, f | - | m, 1, 1 |
| unit vectors, (orthonormal vectors) | i, j, k | i i = j j = k k = 1 i j = j k = k i = 0 | m, 1 |
| position vector | r | r = x i + y j + z k | m |
| generalized coordinates | q, qi | - | (varies) |
| Distance | d | - | m |
| Length | l | - | m |
| height | h | - | m |
| width | w | - | m |
| breadth | b | - | m |
| thickness | d, d | - | m |
| radius | r | - | m |
| diameter | d | - | m |
| path | s | - | m |
| length of arc | s | - | m |
| Area | A, As, S | - | m2 |
| Volume | V, v | - | m3 |
| Plane Angle | a, b, g, q, f | a = s/r | 1, rad |
| Solid Angle | w, W | - | 1, sr |
| Time | t | - | s |
| period, (duration) | T | T = t/N | s |
| Frequency | n, f | n = 1/T | Hz |
| angular frequency, circular frequency | w | w =2pn | rad s-1, s-1 |
| characteristic -- time interval -- relaxation time -- time constant | t, T | t = |dt/dlnx| | s |
| Angular Velocity | w | w = df/dt | rad s-1, s-1 |
| Angular Acceleration | w | w = dw/dt | rad s-2, s-2 |
| Velocity | v, u, w, c, r, r´ (r dot, r prime) | v = dr / dt (r, r´) | m s-1 |
| speed | v, u, w, c | v = |v| | m s-1 |
| Acceleration | a, (g) | a = dv/dt | m s-2 |
Classical Mechanics
Course file in .pdf form
| Classical Mechanics | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| Mass | m | standard | kg |
| reduced mass | m | m = m1m2 / (m1 + m2) | kg |
| Density, mass density | r | r = m/V | kg m-3 |
| relative density | d | d = r/r* | 1 |
| surface density | rA , rS | rA = m / A | kg m-2 |
| Specific Volume | u | u = V/m = 1/r | m3 kg-1 |
| moment of inertia | I , J | I = å mi ri2 | kg m2 |
| Momentum | p | p = mv | I, Fritz, N s, kg m s-1 |
| angular momentum, action | L | L = r ´ p | J s, kg m2 s-1, I m |
| Force | F | F = d p/dt = ma | N, kg m s-2 |
| Moment of Force, torque | T , M | T = r ´ F | N m, (J) |
| Energy | E | kg m2 s-2 | J |
| potential energy | Ep , V , F | Ep = ò F ds | J |
| kinetic energy | Ek , T , K | Ek = ½mv2 | J |
| work | W , w | W = ò F ds | J |
| Hamilton function | H | H (q, p) = T (q, p) + V (q) | J |
| Lagrange function | L | L (q, q) = T (q, q) V (q) | J |
| Pressure | p, P | p = F / A | Pa, N m-2 |
| Surface Tension | g, s | g = dW / dA | N m-1, J m-2 |
| weight | G , (W , P ) | G = mg | N |
| Gravitational Constant | G | F = Gm1m2/r2 | N m2 kg-2 |
| normal stress | s | s = F / A | Pa |
| shear stress | t | t = F / A | Pa |
| linear strain, relative elongation | e, e | e = Dl/l | 1 |
| modulus of elasticity, Young's Modulus | E | E = s/e | Pa |
| shear strain | g | g = Dx/d | 1 |
| shear modulus | G | G = t/g | Pa |
| volume strain, bulk strain | q | q = DV/V0 | 1 |
| bulk modulus, compression modulus | K | K = V0(d p/d V) | Pa |
| Viscosity, dynamic viscosity | h, m | tx,z = h(dvx/dz) | Pa s |
| fluidity | f | f = 1/h | m kg-1 s |
| Kinematic Viscosity | n | n = h/r | m2 s-1 |
| friction coefficient | m, f | Ffrict = mFnorm | 1 |
| Power | P | P = dW / dt | W |
| sound energy flux | P, Ps | P = dE / dt | W |
| acoustic reflection factor | r | P = Pt / P0 | 1 |
| acoustic absorption factor | as, a | as = 1 r | 1 |
| acoustic transmission factor | t | t = Ptr / P0 | 1 |
| acoustic dissipation factor | d | d = as t | 1 |
Analytical Classical Dynamics
Course file in .pdf form
Differential Geometry and General Relativity
Course in .pdf form
| Electromagnetism | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| Electric Charge, quantity of electricity | Q | - | C |
| charge density | r | r = Q / V | C m-3 |
| surface charge density | s | s = Q / A | C m-2 |
| Electric Potential | V , f | V = dW / dQ | V, J C-1 |
| electric potential difference | U , DV , Df | U = V 1 V 2 | V |
| Electromotive Force (emf) | E | E = ò F/Q ds | V |
| Electric Field Strength | E | E = F/Q = grad V | V m-1 |
| electric flux | Y | Y = ò D dA | C |
| Electric Displacement | D | D = eE | C m-2 |
| Capacitance | C | C = Q/U | F |
| Permittivity | e | D = eE | F m-1 |
| Permittivity of Vacuum | e0 | e0 = m0-1c0-2 = 8.854 187 817 ¼ ´ 10-12 F m-1 | F m-1 |
| relative permittivity | er | er = e/e0 | 1 |
| dielectric polarization, dipole moment per volume | P | P = D e0E | C m-2 |
| electric susceptibility | ce | ce = er 1 | 1 |
| electric dipole moment | p, m | p = Q r | C m |
| Electric Current | I | I = dQ/dt | A |
| electric current density | j, J | I = ò j dA | A m-2 |
| polarizability (of a particle) | a | - | m2 C V-1 |
| Magnetic Flux Density, magnetic induction | B | F = Q v ´ B | T |
| Magnetic Flux | F | F = ò B dA | Wb |
| Magnetic Field Strength | H | B = mH | A m-1 |
| Permeability | m | B = mH | H m-1, (N A-2) |
| Permeability of Vacuum | m0 | m0 = 4p ´ 10-7 H m-1 (N A-2) = 12.566 370 614 ¼ ´ 10-7 H m-1 (N A-2) | H m-1, (N A-2) |
| relative permeability | mr | mr = m/m0 | 1 |
| magnetization, magnetic dipole moment per volume | M | M = B/m0 H | A m-1 |
| magnetic susceptibility | c, k, cm | c = mr 1 | 1 |
| molar magnetic susceptibility | cm | cm = Vm c | m3 mol-1 |
| magnetic dipole moment | m, m | Ep = m B | A m2, J T-1 |
| Electrical Resistance | R | R = U / I | W |
| Electrical Conductance | G | G = 1/R | S |
| loss angle | d | d = (p/2) + fI fU | 1, rad |
| reactance | X | X = ( U / I ) sin d | W |
| impedance, complex impedance | Z | Z = R + iX | W |
| admittance, complex admittance | Y | Y = 1/Z | S |
| suseptance | B | Y = G + iB | S |
| Electrical Resistivity | r | r = E / j | W m |
| Electrical Conductivity | k, g, s | k = 1/r | S m-1, (W-1 m-1) |
| (self) Inductance | L | E = L (dI /dt) | H |
| mutual inductance | M, L1 2 | E1 = L1 2 dI2/dt | H |
| magnetic vector potential | A | B = Ñ ´ A | Wb m-1 |
| Poynting vector | S | S = E ´ H | W m-2 |
Classical Electromagnetism
Course file in .pdf form
Differential Forms in Electromagnetic Theory
Course file in .pdf form
| Quantum Mechanics | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| momentum operator | p | p = i | m-1 J s (I, Fritz, N s, kg m s-1) |
| kinetic energy operator | T | T = ( | J |
| hamiltonian operator | H | H = T + V | J |
| wave function, state function | Y, y, f | Hy = Ey | m-3/2 |
| probability density | P | P = y*y | m-3 |
| charge density of electrons | r | r = eP | C m-3 |
| probability current density | S | S = i | m-2 s-1 |
| electric current, density of electrons | j | j = eS | A m-2 |
| matrix elements of operator  | Aij , ái |  | jñ | Aij = ò yi*Âyj dt | (varies) |
| expectation value of operator  | á A ñ, A | á A ñ = ò y*Ây dt | (varies) |
| hermitian conjugate of operator  |  | (  )ij = ( Aji )* | (varies) |
| commutator of  and Ê | [Â, Ê], [Â, Ê]- | [Â, Ê] = Â Ê Ê Â | (varies) |
| anticommutator of  and Ê | [Â, Ê]+ | [Â, Ê] = Â Ê + Ê Â | (varies) |
| spin wavefunction | a, b | - | 1 |
| coulomb integral | HAA | HAA = ò yA*HyA dt | J |
| resonance integral | HAB | HAB = ò yA*HyB dt | J |
| overlap integral | SAB | SAB = ò yA*yB dt | 1 |
The Dirac Formalism of Quantum Mechanics (PDF File)
| Atoms and Molecules | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Name | Symbol | Definition | SI Units | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| number of Entities (atoms, molecules, ions, formula units ) | N | N = {1, 2, 3
N , N + 1, N + 2, N + 3
2N N 2 N N N N N } | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| nucleon number, mass number | A | - | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Proton number, atomic number | Z | - | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Neutron number | N | N = A Z | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Electron Rest Mass | me | me = 9.109 381 88 (72) ´ 10-31 kg | kg | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| mass of atom, atomic mass | ma, m | - | kg | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Atomic Mass Constant | mu | mu = ma(12C)/12 = 10-3 kg mol-1/NA = 1.660 538 73 (13) ´ 10-27 kg = 1 Dalton (Da) | kg | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| mass excess | D | D = ma Amu | kg | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Elementary Charge, Proton Charge | e | e = 1.602 176 462 (63) ´ 10-19 C | C | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Planck Constant | h | h = 6.626 068 76 (52) ´ 10-34 J s (I m) | J s (I m) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Reduced Planck Constant (h bar), Planck Constant/2p | J s (I m) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Bohr Radius | a0 | a0 = a/4pR¥ = 4pe0 = 0.529 177 208 3 (19) ´ 10-10 m | m | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Hartree Energy | Eh | Eh = e2/4pe0a0 = 2R¥hc = a2mec2 = | J | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Rydberg Constant | R¥ | R¥ = meca2/2h = Eh/2hc = 10 973 731.568 549 (83) m-1 | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Fine Structure Constant | a | a = m0ce2/2h = e2/2he0c = 7.297 352 533 (27) ´ 10-3 | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Inverse Fine Structure Constant | a-1 | a-1 = 2h/e2m0c = e0c2h/e2 = 137.035 999 76 (50) | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| ionization energy | Ei , I | - | J | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| electron affinity | Eea | - | J | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| dissociation energy | Ed, D | - | J | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- from ground state | Do | - | J | -- from the potential minimum | De | - | J | principal quantum number (Hydrogen atom) | n | E = hcR/n2 | 1 | Angular Momentum Quantum Numbers | See Under Spectroscopy | magnetic dipole moment of a molecule | m, m | Ep = m B | J T-1, A m2 | magnetizability of a molecule | x | m = xB | J T-2 | Bohr Magneton | mB | mB = e | = 9.274 008 99 (37) ´ 10-24 J T-1 J T-1 | Nuclear Magneton | mN | mN = (me/mp)mB = e | = 5.050 783 17 (20) ´ 10-27 J T-1 J T-1 | magnetogyric ratio, gyromagnetic ratio | g | g = m/L (L = angular momentum) | s-1 T-1, C kg-1 | g - factor | g | - | 1 | Larmor circular frequency | wL | wL = (e/2m)B | s-1 | Larmor frequency | nL | nL = wL/2p | Hz | longitudinal relaxation time | T1 | - | s | transverse relaxation time | T2 | - | s | electric dipole moment of a molecule | p, m | Ep = p E | C m | quadrupole moment of a molecule | Q, Q | Ep = ½Q : V ² = 1/3Q | C m2 | quadrapole moment of a nucleus | eQ | eQ = 2 á Qzz ñ | C m2 | electric field gradient tensor | q | qab = ¶2V/¶a¶b | V m-2 | quadrapole interaction energy tensor | c | cab = eQqab | J | electric polarizability of a molecule | a | p (induced) = aE | C m2 V-1 | activity (of a radioactive substance) | A | A = dNB/dt | Bq | decay (rate) constant, disintegration (rate) constant | l | A = lNB | s-1 | half life | t½, T½ | - | s | mean life | t | - | s | level width | G | G = | J | disintegration energy | Q | - | J | cross section (of a nuclear reaction) | s | - | m2 | | ||
| Statistical Mechanics | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| number of Entities (atoms, molecules, ions, formula units ) | N | N = {1, 2, 3
N , N + 1, N + 2, N + 3
2N N 2 N N N N N } | 1 |
| number density of Entities, number concentration | n, C | n = N /V | m-3 |
| Avogadro Constant, Avogadro's Number | L, NA | NA = 6.022 141 99 (47) ´ 1023 mol-1 | mol-1 |
| Boltzmann Constant | k, kB | R/NA = 1.380 650 3 (24) ´ 10-23 J K-1 | J K-1 |
| Molar Gas Constant | R | R = NAk = 8.314 472 (15) J K-1 mol-1 | J K-1 mol-1 |
| molecular position vector | r (x, y, z) | - | m |
| molecular velocity vector | c (cx, cy, cz), u (ux, uy, uz) | c = dr / dt (r, r´) (r dot, r prime) | m s-1 |
| molecular momentum vector | p (px, py, pz) | p = m c | I, N s, kg m s-1 |
| velocity distribution function (Maxwell) | f (cx) | f (cx) = (m/2pkT )½ ´ exp( mcx2/2kT ) | m-1 s |
| speed distribution function (Maxwell-Boltzmann) | F (c) | F (c) = (m/2pkT )3/2 ´ 4pc2exp( mc2/2kT ) | m-1 s |
| average speed | c, u, ácñ, áuñ | c~ = ò c F(c) dc | m s-1 |
| generalized coordinate | q | - | (m) |
| generalized momentum | p | p = ¶L / ¶q (q dot) | (I, N s, kg m s-1) |
| volume in phase space | W | W = (1/h)ò p dq | 1 |
| probability | P | - | 1 |
| statistical weight, degeneracy | g, d, W , w, b | - | 1 |
| density of (energy) states | r(E) | r(E) = dN / dE | J-1 |
| partition function, sum over states | Symbol | Definition | SI Units |
| -- for a single molecule | q, z | q = åi gi exp( ei/kT ) | 1 |
| -- for a canonical ensemble (system or assembly) | Q , Z | - | 1 |
| microcanonical ensemble | W | - | 1 |
| grand canonical ensemble | X | - | 1 |
| symmetry number | s, s | - | 1 |
| reciprocal temperature | b | b = 1/kT | J-1 |
| charateristic temperature | Q | - | K |
Thermodynamics and Statistical Mechanics
Course file in .pdf form
| Electromagnetic Radiation | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| Wavelength | l | - | m |
| Speed of Light in vacuum | c0 | c0 = 299 792 458 m s-1 (exact) | m s-1 |
| Speed of Light in a medium | c | c = c0/n | m s-1 |
| Wavenumber in vacuum | n | n = n/c0 = 1/nl | m-1 |
| Wavenumber in a medium | s, (k) | s = 1/l | m-1 |
| Frequency | n | n = c/l | Hz |
| circular frequency, pulsatance | w | w = 2pn | s-1, rad s-1 |
| refractive index | n | n = c0/c | 1 |
| Planck Constant | h | h = 6.626 068 76 (52) ´ 10-34 J s (I m) | J s (I m) |
| Reduced Planck Constant | J s (I m) | ||
| radiant energy | Q, W | - | J |
| radiant energy density | r, w | r = Q / V | J m-3 |
| spectral radiant energy density | Symbol | Definition | SI Units |
| -- in terms of frequency | rn, wn | r = dr/dn | J m-3 Hz-1 |
| -- in terms of wavenumber | rn, wn | r = dr/dn | J m-2 |
| -- in terms of wavelength | rl, wl | r = dr/dl | J m-4 |
| Einstein transition probabilities | Symbol | Definition | SI Units |
| -- spontaneous emission | Anm | dNn / dt = Anm Nn | s-1 |
| -- stimulated emission | Bnm | dNn / dt = rn (nnm) ´ Bnm Nn | s kg-1 |
| -- stimulated absorption | Bnm | dNn / dt = rn (nnm) ´ Bnm Nn | s kg-1 |
| radiant power, radiant energy per time | F, P | F = dQ/dt | W |
| radiant intensity | I | I = dF/dW | W sr-1 |
| radiant exitance (emitted radiant flux) | M | M = dF/dAsource | W m-2 |
| irradiance | E, (I ) | E = dF/dA | W m-2 |
| emittance, emissivity | e | e = M / Mbb | 1 |
| Stefan-Boltzmann Constant | s | Mbb = sT 4 = (p2/60)k4/ = 5.670 400 (40) ´ 10-8 W m-2 K-4 | W m-2 K-4 |
| First Radiation Constant | c1 | c1 = 2phc02 = 3.741 771 07 (93) ´ 10-16 W m2 | W m2 |
| Second Radiation Constant | c2 | c2 = hc0/k = 0.014 387 752 (25) m K | m K |
| transmittance, transmission factor | t, T | t = Ftr/F0 | 1 |
| absorptance, absorbtion factor | a | a = Fabs/F0 | 1 |
| reflectance, reflection factor | r | r = Frefl/F0 | 1 |
| (decadic) absorbance | A | A = lg(1 ai) | 1 |
| naperian absorbance | B | B = ln(1 ai) | 1 |
| absorption coefficients | Symbol | Definition | SI Units |
| -- (linear) decadic | a, K | a = A/l | m-1 |
| -- (linear) naperian | a | a = B/l | m-1 |
| -- molar (decadic) | e | e = a/c = A/cl | m2 mol-1 |
| -- molar naperian | k | k = a/c = B/cl | m2 mol-1 |
| complex refractive index | n | n = n + ik | 1 |
| molar refraction | R, Rm | R = [(n2 1)/(n2 + 2)] ´ Vm | m3 mol-1 |
| angle of optical rotation | a | - | 1, rad |
Electromagnetism and Optics
Course files in .pdf form
Advanced Classical Electromagnetism
Course files in .pdf form
| Spectroscopy | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Name | Symbol | Definition | SI Units | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| total term | T | T = Etot/hc | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| transition wavenumber | n, (n) | n = T ¢ T ² | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| transition frequency | n | n = (E¢ E²)/h | Hz | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| electronic term | Te | Te = Ee/hc | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| vibrational term | G | G = Evib/hc | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| rotational term | F | F = Erot/hc | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| spin orbit coupling constant | A | Ts.o. = AáL Sñ | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| principle moments of inertia | IA ; IB ; IC | IA £ IB £ IC | kg m2 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| rotational constants (in wavenumbers) | Ã ; B; C | Ã = h/8p2cIA | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| rotational constants (in frequency) | A, B, C | A = h/8p2IA | Hz | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| inertial defect | D | D = IC IA IB | kg m2 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| asymmetry parameter | k | k = (2B A C)/(A C) | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| centrifugal distortion constants | Symbol | Definition | SI Units | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- S reduction | DJ ; DJK ; DK ; d1; d2 | - | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- A reduction | DJ ; DJK ; DK ; dJ ; dK | - | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| harmonic vibration number | we, wr | - | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| vibrational anharmicity constant | wexe ; xrs ; gn´ | - | m-1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| vibrational quantum numbers | ur ; lt | - | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Coriolis zeta constant | zrsa | - | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Angular Momentum Quantum Numbers : see additional Information below | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| degeneracy, statistical weight | g, d, b | - | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| electric dipole moment of a molecule | p, m | Ep = p E | C m | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| transition dipole moment of a molecule | M, R | M = ò y¢ p y² dt | C m | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| molecular geometry, interatomic distances | Symbol | Definition | SI Units | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- equilibrium distance | re | - | m | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- zero-point average distance | rx | - | m | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- ground state distance | r0 | - | m | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- substitution structure distance | rs | - | m | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| vibrational coordinates | Symbol | Definition | SI Units | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- internal coordinates | R i, ri, q j, etc. | - | (varies) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- symmetry coordinates | S i | - | (varies) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- normal coordinates | Symbol | Definition | SI Units | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| ---- mass adjusted | Q r | - | kg½ m | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| ---- dimensionless | qr | - | 1 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| vibrational force constants | Symbol | Definition | SI Units | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- diatomic | , (k) | = ¶ 2V / ¶ r 2 | J m-2 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| -- polyatomic | Symbol | Definition | SI Units | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| ---- internal coordinates | ij | ij = ¶ 2V / ¶ ri ¶ rj | (varies) | ---- symmetry coordinates | Fij | Fij = ¶ 2V / ¶ S i ¶ S j | (varies) | ---- dimensionless normal coordinates | frst
, krst
| - | m-1 | Nuclear Magnetic Resonance (NMR) | Symbol | Definition | SI Units | -- magnetogyric ratio | g | g = m / I | s-1 T-1, C kg-1 | -- shielding constant | sA | BA = (1 sA) B | 1 | -- chemical shift, d scale | d | d = 106 (n n0) / n0 | 1 | -- (indirect) spin-spin coupling constant | JAB | H/ h = JAB Î A Î B | Hz | -- direct (dipolar) coupling constant | DAB | - | Hz | longitudinal relaxation time | T1 | - | s | transverse relaxation time | T2 | - | s | Electron Spin Resonance (ESR) | Electron Paramagnetic Resonance (EPR) Symbol | Definition | SI Units | -- magnetogyric ratio | g | g = m / s | s-1 T-1, C kg-1 | -- g factor | g | hn = gmBB | 1 | -- hyperfine coupling constant | Symbol | Definition | SI Units | ---- in liquids | a, A | Hhfs / h = a S Î | Hz | ---- in solids | T | Hhfs / h = S T Î | Hz | |
| Angular Momentum Quantum Numbers | ||||
|---|---|---|---|---|
| Angular Momentum | Operator Symbol | Quantum Number Symbol | ||
| Total | Z-axis | z-axis | ||
| electron orbital | L | L | ML | L |
| -- one electron only | l | l | ml | l |
| electron spin | S | S | MS | S |
| -- one electron only | s | s | ms | s |
| electron orbital + spin | L + S | - | - | W = L + S |
| nuclear orbital (rotational) | R | R | - | KR , kR |
| nuclear spin | Î | I | MI | - |
| internal vibrational | - | - | - | - |
| -- spherical top | l | l (lz) | - | Kl |
| -- other | j, p | - | - | l (lz) |
| sum of R + L (+ j) | N | N | - | K , k |
| sum of N + S | J | J | MJ | K , k |
| sum of J + I | F | F | MF | - |
| Solid State Physics | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| lattice vector | R, R0 | - | m |
| fundamental translation vectors for the crystal lattice | a1; a2; a3, a, b, c | R = n1a1 + n2a2 + n3a3 | m |
| (circular) reciprocal lattice vector | G | G R = 2pm | m-1 |
| (circular) fundamental translation vectors of the reciprocal lattice | b1; b2; b3, a*; b*; c* | ai bk = 2pdik | m-1 |
| lattice plane spacing | d | - | m |
| Bragg angle | q | nl = 2d sin q | 1, rad |
| order of reflection | n | - | 1 |
| order parameters | Symbol | Definition | SI Units |
| -- short range | s | - | 1 |
| -- long range | s | - | 1 |
| Burgers vector | b | - | m |
| particle position vector | r, R j | - | m |
| equilibrium position vector of an ion | R0 | - | m |
| displacement vector of an ion | u | u = R R0 | m |
| Debye-Waller factor | B, D | - | 1 |
| Debye circular wavenumber | qD | - | m-1 |
| Debye circular frequency | wD | - | s-1 |
| Grüneisen parameter | g, G | g = aV/kCv | 1 |
| Madelung constant | a, M | Ecoul = aNAz+ze2/4pe0pR0 | 1 |
| density of states | NE | dN(E)/dE | J-1 m-3 |
| (spectral) density of vibrational modes | Nw, g | Nw = dN(w)/dw | s m-3 |
| resistivity tensor | rik | E = r j | W m |
| conductivity tensor | sik | s = r-1 | S m-1, (W-1 m-1) |
| thermal conductivity tensor | lik | Jq = l grad T | W m-1 K-1 |
| residual resistivity | rR | - | W m |
| relaxation time | t | t = l / vF | s |
| Lorenz coefficient | L | L = l / sT | V2 K-2 |
| Hall coefficient | AH, RH | E = r j + RH (B ´ j ) | m3 C-1 |
| Peltier coefficient | P | - | V |
| Thomson coefficient | m, (t) | - | V K-1 |
| work function | F | F = E¥ EF | J |
| number density, number concentration | n, (r) | - | m-3 |
| gap energy | Eg | - | J |
| donor ionization energy | Ed | - | J |
| acceptor ionization energy | Ea | - | J |
| Fermi energy | EF, eF | - | J |
| Fermi temperature | TF | EF = kBTF | K |
| circular wave vector, propogation vector | k, q | k = 2p/l | m-1 |
| Bloch function | uk(r) | y(r) = uk(r) exp(k r) | m-3/2 |
| charge density of electrons | r | r(r) = ey*(r)y(r) | C m-3 |
| effective mass | m* | - | kg |
| mobility | m | m = vdrift / E | m2 V-1 s-1 |
| mobility ratio | b | b = mn/mp | 1 |
| diffusion coefficient | D | dN/dt = D A(dn/dx) | m2 s-1 |
| diffusion length | L | L = (Dt)½ | m |
| characteristic (Weiss) temperature | q, qW | - | K |
| Curie temperature | TC | - | K |
| Néel temperature | TN | - | K |
| superconducting critical transition temperature | Tc | - | K |
Crystallographic Teaching Pamphlets
Matrices, Mappings, and Crystallographic Symmetry
Course file in .pdf form
Britney Spears Guide to Semiconductor Physics
Principles of Semiconductor Devices
Physical Properties of Semiconductors
| General Chemistry | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| number of Entities (atoms, molecules, ions, formula units ) | N | N = {1, 2, 3
N , N + 1, N + 2, N + 3
2N N 2 N N N N N } | 1 |
| amount of substance, chemical amount | n | nB = NB/L (L = Avogadro's Constant) | mol |
| Avogadro Constant, Avogadro's Number | L, NA | L = 6.022 141 99 (47) ´ 1023 mol-1 | mol-1 |
| mass of atom, atomic mass | ma, m | - | kg |
| mass of entity, molecule or formula unit | mf , m | - | kg |
| Atomic Mass Constant | mu | mu = ma(12C)/12 = 10-3 kg mol-1/NA = 1.660 538 73 (13) ´ 10-27 kg = 1 Dalton (Da) | kg |
| Molar Mass | M | MB = m/nB | kg mol-1 |
| relative molecular mass, (relative molar mass, molecular weight) | Mr | Mr, B = mB/mu | 1 |
| relative atomic mass, (atomic weight) | Ar | Ar = ma/mu | 1 |
| Molar Volume | Vm | Vm, B = V / nB | m3 mol-1 |
| mass fraction | w | wB = mB / åi mi | 1 |
| volume fraction | f | fB = VB / åi Vi | 1 |
| mole fraction, amount fraction, number fraction | x, y | xB = nB / åi ni | 1 |
| (total) Pressure | p, P | - | Pa |
| partial pressure of substance B | pB | pB = yB p | Pa |
| mass concentration (Mass Density) | g, r | gB = mB / V | kg m-3 |
| number concentration, number density of Entities | C, n | CB = NB / V | m-3 |
| amount concentration (concentration of substance B) | c, cB, [B] | cB = nB / V | mol m-3 |
| solubility | s | sB = cB (saturated solution) | mol m-3 |
| molality (of a solute) | m, (b) | mB = nB/mA | mol kg-1 |
| surface concentration | G | GB = nB / A | mol m-2 |
| stoichiometric number | n | - | 1 |
| extent of reaction, advancement | x | Dx = nB/nB | mol |
| degree of dissociation | a | - | 1 |
| Thermodynamics | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| Heat | q, Q | - | J |
| work | w, W | - | J |
| internal Energy | U | DU = q + w | J |
| enthalpy | H | H = U + pV | J |
| thermodynamic Temperature | T | - | K |
| Celsius Temperature | q, t | q / ºC = T / K 273.15 | ºC |
| Entropy | S | dS ³ dq/T | J K-1 |
| Helmholtz energy (Helmholtz function) | A | A = U T S | J |
| Gibbs energy (Gibbs function) | G | G = H T S = U + p V T S | J |
| Massieu function | J | J = A / T | J K-1 |
| Planck function | Y | Y = G / T | J K-1 |
| Surface Tension | g, s | g = ( ¶G / ¶ As )T , p | J m-2, N m-1 |
| molar quantity X | X m | X m = X / n | (varies) |
| specific quantity X | x | x = X / m | (varies) |
| pressure coefficient | b | b = (¶ p / ¶T )V | Pa K-1 |
| relative pressure coefficient | a p | a p = (1 / p)(¶ p / ¶T )V | K-1 |
| isothermal compressibility | kT | kT = (1/V )( ¶V / ¶ p )T | Pa-1 |
| isentropic compressibility | kS | kS = (1/V )( ¶V / ¶ p )S | Pa-1 |
| linear expansion coefficient | al | al = (1 / l )(¶ l / ¶T ) | K-1 |
| cubic expansion coefficient | a, aV , g | a = (1/V )(¶V / ¶T ) p | K-1 |
| Heat Capacity (at constant pressure) | Cp | Cp = (¶H / ¶T ) p | J K-1 |
| Heat Capacity (at constant volume) | CV | CV = (¶H / ¶T )V | J K-1 |
| ratio of heat capacities | g, (k) | g = Cp / CV | 1 |
| Joule-Thomson coefficient | m, mJT | m = (¶T / ¶ p )H | K Pa-1 |
| second virial coefficient | B | pVm = RT (1 + B/Vm + ) | m3 mol-1 |
| compression factor (compressibility factor) | Z | Z = pVm / RT | 1 |
| partial molar quantity X | XB, (X ¢B) | XB = ( ¶ X / ¶nB )T , p , n j ¹ B | (varies) |
| chemical potential (partial molar Gibbs energy) | m | ¶B = ( ¶G / ¶nB )T , p , n j ¹ B | J mol-1 |
| absolute activity | l | lB = exp(mB / RT ) | 1 |
| standard chemical potential | m | - | J mol-1 |
| standard partial molar enthalpy | HB | HB | J mol-1 |
| standard partial molar entropy | SB | SB | J mol-1 K-1 |
| standard reaction Gibbs energy (function) | Dr G | Dr G | J mol-1 |
| affinity of reaction | A, A | A = ( ¶G / ¶x )T , p = åB nBmB | J mol-1 |
| standard reaction enthalpy | Dr H | Dr H | J mol-1 |
| standard reaction entropy | Dr S | Dr S | J mol-1 K-1 |
| equilibrium constant | K | K | 1 |
| -- pressure basis | Kp | Kp = ÕB pBnB | Pa Sn |
| -- concentration basis | Kc | Kc = ÕB cBnB | (mol m-3) Sn |
| -- molality basis | Km | Km = ÕB mBnB | (mol kg-1) Sn |
| fugacity | f, p~ | fB = lB limp ® 0 ( pB/lB)T | Pa |
| fugacity coefficient | f | fB = fB / pB | 1 |
| activity and activity coefficient referenced to Raoult's law | |||
| -- (relative) activity | a | aB = exp[(mB mB*) / RT] | 1 |
| -- activity coefficient | f | fB = aB / xB | 1 |
| activity and activity coefficient referenced to Henry's law | |||
| -- (relative) activity | Symbol | Definition | SI Units |
| ---- molality basis | am | am, B = exp[(mB mB | 1 |
| ---- concentration basis | ac | ac, B = exp[(mB mB | 1 |
| ---- mole fraction basis | ax | ax, B = exp[(mB mB | 1 |
| -- activity coefficient | Symbol | Definition | SI Units |
| ---- molality basis | gm | am, B = gm, B mB / m | 1 |
| ---- concentration basis | gc | ac, B = gc, B cB / c | 1 |
| ---- mole fraction basis | gx | ax, B = gx, B xB | 1 |
| ionic strength | Symbol | Definition | SI Units |
| -- molality basis | I m, I | I m = ½ åB mB zB2 | mol kg-1 |
| -- concentration basis | I c, I | I c = ½ åB cB zB2 | mol m-3 |
| osmotic coefficient | Symbol | Definition | SI Units |
| -- molality basis | fm | fm = (mA* mA) / ( RT MA å mB ) | 1 |
| -- mole fraction basis | fx | fx = (mA mA*) / ( RT ln xA ) | 1 |
| osmotic opressure | P | P = cB RT (ideal dilute solution) | Pa |
| Thermodynamic Functions and Relations | ||
|---|---|---|
| Name | Symbol | Relation |
| amount of substance - i | ni | mol (mole), integer - n |
| mole fraction of substance - i | xi | xi = ni / å j n j |
| Volume | V | m3 |
| Pressure | p | Pa (Pascal), N m-2 |
| Temperature | T | K (Kelvin) |
| Energy | U | J (Joule), kg m2 s-2 |
| Entropy | S | dS ³ dq/T (J/K) |
| Enthalpy | H | H = U + p V |
| Helmholtz energy | A | A = U T S |
| Gibbs energy | G | G = U + p V T S = H T S |
| isobaric heat capacity | Cp | Cp = ( ¶H / ¶T ) p |
| isochoic heat capacity | CV | CV = ( ¶U / ¶T )V |
| isobaric expansivity | a | a = V -1 ( ¶V / ¶T ) p |
| isothermal compressibility | kT | kT = V -1 ( ¶V / ¶ p )T |
| isentropic compressibility | kS | kS = V -1 ( ¶V / ¶ p )S |
| - | - | Cp CV = T a2 V / kT |
| - | - | kT kS = T a2 V / Cp |
| Gibbs - Helmholtz equation | - | H = G T ( ¶G / ¶T ) p |
| Maxwell relations | - | ( ¶S / ¶ p )T = ( ¶V / ¶T ) p ( ¶S / ¶V )T = ( ¶ p / ¶T )V |
| Joule - Thomson expansion | mJT | mJT = ( ¶T / ¶ p )H = [ V T ( ¶V / ¶T ) p ] / Cp |
| Joule - Thomson expansion | fJT | fJT = ( ¶H / ¶ p )T = V T ( ¶V / ¶T ) p |
| partial molar quantity | X i | X i = ( ¶ X / ¶n i )T , p , n j ¹ i |
| chemical potential | mi | mi = ( ¶G / ¶n i )T , p , n j ¹ i |
| perfect gas | pg | pV = å i n i RT |
| perfect gas | pg | mpg = mi (Superscript |
| fugacity | fi | fi = (xi p ) exp [mi mipg / RT ] |
| activity coefficient | gi | gi = fi / xi fi (Superscript |
| Gibbs - Duhem relation | - | 0 = S dT V d p + å i n i dmi |
| Notation for Chemical and Physical Changes | ||
|---|---|---|
| Recommended Subscripts (X = H , S , G , etc.) | ||
| Chemical Change | Subscript | Symbol |
| chemical reaction | r | Dr X |
| Formation from Elements | f | Df X |
| combustion | c | Dc X |
| melting, fusion (solid « liquid) | fus | Dfus X |
| vaporization, evaporation (liquid ® gas) | vap | Dvap X |
| sublimation (solid ® gas) | sub | Dsub X |
| phase transition | trs | Dtrs X |
| solution (of a solute in a solvent) | sol | Dsol X |
| mixing (of two fluids) | mix | Dmix X |
| dilution (of a solution) | dil | Ddil X |
| adsorption | ads | Dads X |
| displacement | dpl | Ddpl X |
| immersion | imm | Dimm X |
| atomization | at | Dat X |
| Recommended Superscripts | |
|---|---|
| Chemical State | Superscript |
| standard state | |
| pure substance | * |
| infinite dilution | ¥ |
| ideal | id |
| activated complex, transition state | |
| excess quantity | E |
| Chemical Kinetics | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| rate of change of quantity X | X | X = dX/dt | (varies) |
| rate of conversion | x | x = dx/dt | mol s-1 |
| rate of concentration change of substance B (due to chemical reaction) | rB, vB | rB = dcB/dt | mol m-3 s-1 |
| rate of reaction (based on amount concentration) | v | v = x/V = nB-1 dcB/dt | mol m-3 s-1 |
| partial order of reaction | nB | v = k ÕB cBnB | 1 |
| overall order of reaction | n | n = åB nB | 1 |
| rate constant, rate coefficient | k | v = k ÕB cBnB | (m3 mol-1) n - 1 s-1 |
| Boltzmann Constant | k, kB | kB = R/NA = 1.380 650 3 (24) ´ 10-23 J K-1 | J K-1 |
| half life | t½ | c(t½) = c0/2 | s |
| relaxation time | t | t = 1/(k1 + k-1) | s |
| energy of activation, activation energy | Ea, E | Ea = RT 2 d ln k/dT | J mol-1 |
| pre-exponential factor | A | k = A exp( Ea/RT ) | (m3 mol-1) n - 1 s-1 |
| volume of activation | DV | DV = RT ( ¶ ln k/¶ p)T | m3 mol-1 |
| collision diameter | d | dAB = rA + rB | m |
| collision cross section | s | sAB = pdAB | m2 |
| collision frequency | ZA | - | s-1 |
| collision number | ZAB, ZAA | - | m-3 s-1 |
| collision frequency factor | zAB, zAA | zAB = ZAB/LcAcB | m3 mol-1 s-1 |
| standard enthalpy of activation | DH | - | J mol-1 |
| standard entropy of activation | DS | - | J mol-1 K-1 |
| standard Gibbs energy of activation | DG | - | J mol-1 |
| quantum yield, photochemical yield | f | - | 1 |
| Electrochemistry | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| Elementary Charge, Proton Charge | e | e = 1.602 176 462 (63) ´ 10-19 C | C |
| Faraday Constant | F | F = eL = 96 485.341 5 (39) C mol-1 | C mol-1 |
| charge number of an ion | z | zB = QB/e | 1 |
| ionic strength | Symbol | Definition | SI Units |
| -- concentration basis | I c, I | I c = ½ åi ci zi2 | mol m-3 |
| -- molality basis | I m, I | I m = ½ åi mi zi2 | mol kg-1 |
| mean ionic activity | a± | a± = m± g± / m | 1 |
| mean ionic molality | m± | m±n+ + n = m+n+ mn | mol kg-1 |
| mean ionic activity coefficient | g± | g±n+ + n = g+n+ gn | 1 |
| charge number of electrochemical cell reaction | n, (z) | - | 1 |
| electric potential difference (of a galvanic cell) | DV , E, U | DV = V R V L | V |
| Electromotive Force, emf, electrode potential | E | E = limI ® 0 DV | V |
| standard emf, standard potential of the electrochemical cell reaction | E | E | V |
| standard electrode potential | E | - | V |
| emf of the cell, potential of the electrochemical cell reaction | E | E = E | V |
| pH | pH | pH » lg [c(H +) / mol dm-3] | 1 |
| inner electric potential | f | Ñf = E | V |
| outer electric potential | y | y = Q/4pe0r | V |
| surface electric potential | c | c = f y | V |
| Galvani potential difference | Df | Dfab = fb fa | V |
| Volta potential difference | Dy | Dyab = yb ya | V |
| electrochemical potential | m~ | m~Ba = ( ¶G / ¶nBa ) | J mol-1 |
| Electric Current | I | I = dQ/dt | A |
| (electric) current density | j | j = I / A | A m-2 |
| (surface) charge density | s | s = Q / A | C m-2 |
| electrode reaction rate constant | k | kox = Ia / nFA Õi cini | (varies) |
| mass transfer coefficient, diffusion rate constant | kd | kd, B = | vB | Il, B / nFcA | m s-1 |
| thickness of a diffusion layer | d | dB = DB / kd, B | m |
| transfer coefficient (electrochemical) | a | ac = (|v|RT/nF)(¶ ln |Ic| / ¶E ) | 1 |
| overpotential | h | h = EI EI = 0 I Ru | V |
| electrokinetic potential (zeta potantial) | z | - | V |
| Conductivity | k, (s) | k = j / E | S m-1, (W-1 m-1) |
| conductivity cell constant | Kcell | Kcell = k R | m-1 |
| molar conductivity (of an electrolyte) | L | L = k / cB | S m2 mol-1 |
| ionic conductivity, molar conductivity of an ion | l | l = | zB | F uB | S m2 mol-1 |
| electric mobility | u, (m) | uB = vB / E | m2 V-1 s-1 |
| transport number | t | tB = jB / åi ji | 1 |
| reciprocal radius of ionic atmosphere | k | k = (2F 2I / eRT)½ | m-1 |
| Surface Properties | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| specific surface area | a, as, s | a = A/m | m2 kg-1 |
| surface amount of B, adsorbed amount of B | nBs, nBa | - | mol |
| surface excess of B | nBs | - | mol |
| surface excess concentration of B | GB, (GBs ) | GB = nBs / A | mol m-2 |
| total excess surface concentration | G , (G s ) | G = åiGi | mol m-2 |
| area per molecule | a, s | aB = A/NBs | m2 |
| area per molecule in a filled monolayer | am, sm | am, B = A/Nm, B | m2 |
| surface coverage | q | q = NBs/Nm, B | 1 |
| contact angle | q | - | 1, rad |
| film thickness | t, h, d | - | m |
| thickness of (surface or interficial) layer | t, d, t | - | m |
| Surface Tension, interficial tension | g, s | g = ( ¶G / ¶ As )T , p | N m-1, J m-2 |
| film tension | Sf | Sf = 2gf | N m-1 |
| reciprocal thickness of the double layer | k | k = (2F 2Ic / eRT)½ | m-1 |
| average molar masses | Symbol | Definition | SI Units |
| -- number-average | Mn | Mn = åi niMi / åi ni | kg mol-1 |
| -- mass-average | Mm | Mm = åi niMi2 / åi niMi | kg mol-1 |
| -- Z-average | MZ | MZ = åi niMi3 / åi niMi2 | kg mol-1 |
| sedimentation coefficient | s | s = v/a | s |
| van der Waals constant | l | - | J |
| retarded van der Waals constant | b, B | - | J |
| van der Waals - Hamaker constant | AH | - | J |
| surface pressure | ps, p | ps = g 0 g | N m-1 |
| Transport Properties | |||
|---|---|---|---|
| Name | Symbol | Definition | SI Units |
| flux (of a quantity X ) | JX, J | JX = A-1 dX/dt | (varies) |
| volume flow rate | qV, V | qv = dV/dt | m3 s-1 |
| mass flow rate | qm, m | qm = dm/dt | kg s-1 |
| mass transfer coefficient | kd | - | m s-1 |
| heat flow rate | f | f = dq/dt | W |
| heat flux | Jq | Jq = f / A | W m-2 |
| thermal conductance | G | G = f / DT | W K-1 |
| thermal resistance | R | R = 1/G | K W-1 |
| thermal conductivity | l, k | l = Jq / (dT / dl) | W m-1 K-1 |
| coefficient of heat transfer | h, (k, K, a) | h = Jq / DT | W m-2 K-1 |
| thermal diffusivity | a | a = l / rcp | m2 s-1 |
| diffusion coefficient | D | D = Jn / (dc/dl) | m2 s-1 |
The following symbols are used in the definition of the Dimensionless Quantities :
Mass (m), Time (t), Length ( l ), Area (A), Volume (V ), Density (r), Speed (v), Viscosity (h), Pressure (p), Temperature (T ), Surface Tension (g), Acceleration of Free Fall (g), Speed of Sound (c), Mean Free Path (l), Frequency ( f ), Specific Heat Capacity at Constant Pressure (Cp), Cubic Expansion Coefficient (a), Mole Fraction (x), Permeability (m), Electrical Conductivity (k), Magnetic Flux Density (B), Thermal Conductivity (k), Thermal Diffusivity (a), Diffusion Coefficient (D), Coefficient of Heat Transfer (h), and Mass Transfer Coefficient (kd).
| Dimensionless Quantities | |||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Name | Symbol | Definition | SI Units | ||||||||||||
| Reynolds number | Re | Re = rvl/h | 1 | ||||||||||||
| Euler number | Eu | Eu = D p/rv2 | 1 | ||||||||||||
| Froude number | Fr | Fr = v/(lg)½ | 1 | ||||||||||||
| Grashof number | Gr | Gr = l 3gaDT r2/h2 | 1 | ||||||||||||
| Weber number | We | We = rv2l/g | 1 | ||||||||||||
| Mach number | Ma | Ma = v/c | 1 | ||||||||||||
| Knudsen number | Kn | Kn = l/l | 1 | ||||||||||||
| Strouhal number | Sr | Sr = l f /v | 1 | ||||||||||||
| Fourier number | Fo | Fo = at/l 2 | 1 | ||||||||||||
| Péclet number | Pe | Pe = vl/a | 1 | ||||||||||||
| Rayleigh number | Ra | Ra = l 3gaDT r/ha | 1 | ||||||||||||
| Nusselt number | Nu | Nu = hl / k | 1 | ||||||||||||
| Stanton number | St | St = h/rvcp | 1 | ||||||||||||
| Fourier number for mass transfer | Fo* | Fo* = Dt/l 2 | 1 | ||||||||||||
| Grashof number for mass transfer | Gr* | Gr* = l 3g(¶r / ¶x)T, p (Dxr / h) | 1 | ||||||||||||
| Péclet number for mass transfer | Pe* | Pe* = vl / D | 1 | ||||||||||||
| Nusselt number for mass transfer | Nu* | Nu* = kd l / D | 1 | ||||||||||||
| Stanton number for mass transfer | St* | St* = kd / v | 1 | ||||||||||||
| Prandtl number | Pr | Pr = h/ra | 1 | ||||||||||||
| Schmidt number | Sc | Sc = h/rD | 1 | ||||||||||||
| Lewis number | Le | Le = a/D | 1 | ||||||||||||
| Magnetic Reynolds number | Rm, Rem | Rm = vmk l | 1 | Alfvén number | Al | Al = v(r m)½ / B | 1 | Hartmann number | Ha | Ha = B l (k h)½ / B | 1 | Cowling number | Co | Co = B 2/mrv2 | 1 | |
| FAQ : How many Scrunches per inch is that? |
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